π-Extended dibenzo[g,p]chrysenes

文献信息

发布日期 2021-02-20

DOI 10.1039/D1QO00068C

影响因子 5.281

作者

Mohammad Mosharraf Hossain, M. Saeed Mirzaei, Sergey V. Lindeman, Saber Mirzaei, Rajendra Rathore

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摘要

Here, we report two series (denoted as meta and para) of π-extended dibenzo[g,p]chrysenes (DBCs) with different substituents (H, Me and OMe). These six novel compounds benefit from the presence of eight methyl groups on the sp3 bridges which improve the solubility and rigidify the extended phenylenes. Their optoelectronic properties were determined using electrochemistry and spectroscopic (UV-vis and emission) techniques and further confirmed by DFT calculations. The results showed that both the position and nature of substituents on the π-extended moieties exert significant effects on the optoelectronic properties and the charge delocalization mechanism. In addition, isomerism (meta and para) leads to different packings in the solid state structure; interestingly, the crystal structure of the hydrogen substituted para molecule showed a permanent three-dimensional porous structure.

期刊推荐

Journal of Natural Medicines

Chemical Communications

Crystallography Reports

Russian Journal of Coordination Chemistry

New Journal of Chemistry

Russian Journal of General Chemistry

Russian Journal of Bioorganic Chemistry

Acta Materialia

Nature Medicine

Russian Journal of Organic Chemistry

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

π-Extended dibenzo[g,p]chrysenes

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