amine structure](https://cnstatic.chemtradehub.com/structs/629/62924-61-2-0728.webp "[(2-chlorophenyl)methyl](ethyl)amine structure")
Synthetic platform for mono-functionalised tridentate macrocycles as key precursors of mechanically-linked macromolecular systems
文献信息
发布日期
2021-03-08
DOI
10.1039/D1QO00245G
影响因子
5.281
作者
Atul Kumar Sharma, Jagadeesh Malineni, Simon Box, Sina Ghiassinejad, Evelyne van Ruymbeke, Charles-André Fustin
查看原文
摘要
We report here a synthetic platform toward mono-functionalized tridentate macrocycles based on a pyridine-2,6-bis-carboxamide motif. These macrocycles bear a variety of functional groups at the fourth position of the pyridine, giving access to a wide range of synthetic methods for further derivatisation or preparation of more complex structures such as mechanically interlocked molecules or polymer materials. To illustrate the potential of this family of macrocycles a series of square planar palladium complex-based pseudorotaxanes, containing different axles and functional groups on the ring, are synthesised, and then used to prepare a macro-pseudorotaxane, i.e. a polymer containing a rotaxane junction, and mechanically-linked gels by a one-pot and a polyrotaxane approach.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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