Noncovalent interactions in Ir-catalyzed remote C–H borylation: a recent update

文献信息

发布日期 2021-05-08

DOI 10.1039/D1QO00452B

影响因子 5.281

作者

Saikat Pandit, Sudip Maiti, Debabrata Maiti

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摘要

Iridium catalyzed direct C–H borylation has provided a powerful strategy to construct a complex molecular architecture in a relatively straightforward way. Controlling regioselectivity is one of the most challenging issues in these transformations. Enormous efforts of the synthetic community have helped to overcome the selectivity issue in the case of proximal C–H borylation by introducing a directing group concept along with noncovalent interaction. However, selectively targeting a remote C–H bond is a formidable challenge and often requires special designing of the directing template. In this highlight, we aim to provide a recent update on noncovalent interaction enabled Ir-catalyzed remote C–H borylation, with a special emphasis on the corresponding enantioselective variant.

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来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry