Grob-type fragmentation of an oxonium ylide generated from α-imino rhodium carbene
文献信息
发布日期
2021-09-19
DOI
10.1039/D1QO01226F
影响因子
5.281
作者
Tao Chen, Zhenxing Yan, Shengguo Duan, Ze-Feng Xu, Chuan-Ying Li
查看原文
摘要
A Grob-type fragmentation of an oxonium ylide generated from the intramolecular addition of oxygen to α-imino rhodium carbene was realized. The reaction was stereospecific and produced two remote double bonds. The newly formed double bonds could be employed as useful synthetic handles for further transformations. A reasonable mechanism was proposed based on primary control experiments and comparison of the stereochemistry of the starting triazoles with that of the products.
相关文献
Rapid and accurate molecular deprotonation energies from quantum alchemy
Guido Falk von Rudorff, O. Anatole von Lilienfeld
2019-12-19
Paper
DOI: 10.1039/C9CP06471K
Analytical magnetostatic model for 2D arrays of interacting magnetic nanowires and nanotubes
Yenni Velázquez-Galván, Armando Encinas
2020-06-02
Paper
DOI: 10.1039/D0CP00808G
FB-REDA: fragment-based decomposition analysis of the reorganization energy for organic semiconductors
Kun-Han Lin, Clémence Corminboeuf
2020-05-12
Paper
DOI: 10.1039/D0CP01722A
Interface hybridization and spin filter effect in metal-free phthalocyanine spin valves
Xiannian Yao, Lianqun Zhou, Fubo Tian
2020-04-28
Paper
DOI: 10.1039/D0CP00651C
Bi-stimuli assisted engineering and control of magnetic phase in monolayer CrOCl
A. K. Nair, S. Rani, M. Venkata Kamalakar, S. J. Ray
2020-04-17
Paper
DOI: 10.1039/D0CP01204A
Charge fluctuations from molecular simulations in the constant-potential ensemble
Laura Scalfi, Sara Bonella, Paul A. Madden
2019-12-13
Paper
DOI: 10.1039/C9CP06285H
Computational insight into the halogen bonded self-assembly of hexa-coordinated metalloporphyrins
Jyoti Rani, Vratta Grover, Swati Dhamija, Hatem M. Titi
2020-04-20
Paper
DOI: 10.1039/D0CP00351D
Highly efficient energy transfer from a water soluble zinc silver indium sulphide quantum dot to organic J-aggregates
Naupada Preeyanka, Himani Dey, Sudipta Seth, Abdur Rahaman, Moloy Sarkar
2020-05-06
Paper
DOI: 10.1039/D0CP01845G
您可能还喜欢
化合物问答
如何储存1,2-环己二酮环乙缩醛(CAS号：4746-96-7)？
1,2-环己二酮环乙缩醛应储存在阴凉、干燥、通风良好的地方，避免阳光直射。建议使用密封容器保存，并保持环境温度在室温范围内，远离火源和热源。
4746-96-71,4-Dioxaspiro[4.5]d...
化合物问答
Ecopladib(CAS号：381683-92-7)的市场或研究趋势如何？
Ecopladib作为一种新型的药物，主要应用于治疗高胆固醇等疾病。目前，市场和研究趋势显示，Ecopladib因其独特的药理作用而受到关注。随着对心血管疾病治...
381683-92-7Ecopladib
化合物问答
2,3-Dimethyl-3H-imidazo[4,5-c]pyridine(CAS号：52538-09-7)通常如何合成？
2,3-二甲基-3H-咪唑[4,5-c]吡啶通常通过咪唑和2,3-二甲基吡啶的缩合反应合成。具体来说，将咪唑和2,3-二甲基吡啶在适当的溶剂中进行加热或加压反应...
52538-09-72,3-Dimethyl-3H-imid...
化合物问答
2,3,4,5-tetrahydro-1H-3-苯并氮杂环;盐酸盐(CAS号：17379-01-0)的市场或研究趋势如何？
该化合物在药物化学和有机合成中有一定的应用。近年来，随着对新型药物化合物的需求增加，该化合物的研究趋势主要集中在探索其生物活性，尤其是其在神经系统疾病治疗中的潜...
17379-01-02,3,4,5-Tetrahydro-1...
68-90-6(2-Ethyl-1-benzofura...
化合物问答
如何储存盐酸甘氨酸丁酯(CAS号：13048-99-2)？
盐酸甘氨酸丁酯应储存在阴凉、干燥、通风良好的地方，避免阳光直射和高温环境，温度应控制在25℃以下。储存容器应密封，避免与空气中的水分和酸性物质接触，以防发生水解...
13048-99-2Butyl glycinate hydr...
化合物问答
什么是2-Iodo-N,N-dimethylbenzamide(CAS号：54616-46-5)？
2-碘-N,N-二甲基苯胺是一种有机化合物，化学名为2-Iodo-N,N-dimethylbenzamide。其分子式为C<sub>9</sub>H<sub>1...
54616-46-52-Iodo-N,N-dimethylb...
16817-90-6N-Cyclohexylglycinam...
化合物问答
5-溴-2-(4H-1,2,4-三唑-4-基)吡啶(CAS号：959240-99-4)的市场或研究趋势如何？
随着医药、农药和新材料领域的发展，该化合物作为关键中间体的应用日益增多。特别是在药物合成中，由于其独特的化学性质，可以用于合成多种药物分子。未来的研究趋势可能集...
959240-99-45-Bromo-2-(4H-1,2,4-...
化合物问答
2,4-二溴-6-三氟甲基嘧啶(CAS号：785778-00-9)通常如何合成？
2,4-二溴-6-三氟甲基嘧啶通常通过溴化反应合成。首先，将6-三氟甲基嘧啶与溴化剂（如液溴）在适当的溶剂（如二氯甲烷、四氢呋喃）中反应，加入适当的催化剂（如四...
785778-00-92,4-Dibromo-6-(trifl...
来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
推荐化合物
推荐供应商
免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联，也不处理投稿事宜。如有投稿相关咨询，请直接联系相关期刊出版商。
如发现页面信息有误，请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。