Nucleobase-containing polymer architectures controlled by supramolecular interactions: the key to achieve biomimetic platforms with various morphologies
文献信息
Laura Vasilica Arsenie, Vincent Ladmiral, Patrick Lacroix-Desmazes, Sylvain Catrouillet
In biological systems, DNA formation occurs due to complementary H-bond interactions between nucleobases, as well as hydrophobic supramolecular interactions. It inspired polymer chemists in the development of supramolecular artificial platforms based on nucleobase-containing polymers. Despite their biomimetic nature and their huge potential to develop bioinspired supramolecular assemblies, nucleobase-containing polymers are in their infancy. The first part of this review aims to highlight the synthetic challenges related to the synthesis of nucleobase-containing monomers and polymers. The second part illustrates how to guide supramolecular interactions of nucleobase-containing copolymer architectures in order to obtain particular morphologies of the resulting supramolecular systems.
期刊推荐

Journal of Natural Medicines

Russian Journal of Coordination Chemistry

Acta Materialia

Current Opinion in Solid State & Materials Science

Russian Journal of Bioorganic Chemistry

Drug Discovery Today

Russian Journal of General Chemistry

Journal of Peptide Science

Chemistry Education Research and Practice

Nature Medicine
相关文献
Supramolecular flower micelle formation of polyrotaxane-containing triblock copolymers prepared from macro-chain transfer agents bearing molecular hooks
Atsushi Tamura, Hajime Tanaka, Nobuhiko Yui
DOI: 10.1039/C4PY00379A
Dimanganese decacarbonyl/2-cyanoprop-2-yl-1-dithionaphthalate: toward sunlight induced RAFT polymerization of MMA
Xuelang Miao, Jiajia Li, Zhengbiao Zhang, Zhenping Cheng, Wei Zhang, Jian Zhu, Xiulin Zhu
DOI: 10.1039/C4PY00509K
Synthesis of end-functionalized boronic acid containing copolymers and their bioconjugates with rod-like viruses for multiple responsive hydrogels
DOI: 10.1039/C4PY00508B
Nano-building block based-hybrid organic–inorganic copolymers with self-healing properties
A. Guinault, S. Delalande
DOI: 10.1039/C4PY00172A
Phosphazene-catalyzed ring-opening polymerization of ε-caprolactone: influence of solvents and initiators
Haleema Alamri, Junpeng Zhao, David Pahovnik, Nikos Hadjichristidis
DOI: 10.1039/C4PY00493K
Synthesis of cationic poly((3-acrylamidopropyl)trimethylammonium chloride) by SARA ATRP in ecofriendly solvent mixtures
Patrícia V. Mendonça, Dominik Konkolewicz, Saadyah E. Averick, Arménio C. Serra, Anatoliy V. Popov, Tamaz Guliashvili, Krzysztof Matyjaszewski, Jorge F. J. Coelho
DOI: 10.1039/C4PY00707G
Highly pH-sensitive polyurethane exhibiting shape memory and drug release
Ying Li, Ye Liu, Tao Gong, Lin Wang, Shaobing Zhou
DOI: 10.1039/C4PY00474D
Reactive macromolecular micelle crosslinked highly elastic hydrogel with water-triggered shape-memory behaviour
Tingting Zhao, Mei Tan, Yulin Cui, Chao Deng, He Huang, Mingyu Guo
DOI: 10.1039/C4PY00554F
A well-defined coil–comb polycationic brush with “star polymers” as side chains for gene delivery
Mingming Zhang, Qingqing Xiong, Yinsong Wang, Zhibao Zhang, Wei Shen, Lingrong Liu, Quanyao Wang
DOI: 10.1039/C4PY00311J
您可能还喜欢
什么是2,6-二溴-4,8-双[(2-乙基己基)氧基]苯并[1,2-b:4,5-b']二噻吩(CAS号:1226782-13-3)?
2,6-二溴-4,8-双[(2-乙基己基)氧基]苯并[1,2-b:4,5-b']二噻吩是一种有机化合物,分子式为C23H32Br2O2S2。该化合物具有芳香性和...
木聚硫钠(CAS号:37319-17-8)的物理化学性质是什么?
木聚硫钠通常为无色或白色结晶性粉末,具有吸湿性。其分子量约为121.11 g/mol。木聚硫钠易溶于水,不溶于醇类和其他非极性溶剂。在酸性或碱性溶液中,木聚硫钠...
2-甲氧基-4-(三氟甲基)苄溴, JRD(CAS号:886500-59-0)适用哪些法规指南?
该化合物在合成、储存和运输过程中需遵循《全球化学品统一分类和标签制度》(GHS)的健康、环境和物理危险分类。在欧洲还需符合《化学品注册、评估、授权和限制》(RE...
1,4-Diazoniabicyclo[2.2.2]octane-1,4-disulfinate(CAS号:119752-83-9)的主要用途是什么?
1,4-二氮杂双环[2.2.2]辛烷-1,4-二硫酸二酯主要用于有机合成中的保护基团,特别是在保护胺基和硫醇基方面具有广泛应用。此外,它还用于一些特殊化学反应的...
如何处理含有4-(Bromomethyl)-2-fluorobenzenesulphonamide(CAS号:1645275-47-3)的废料?
含有4-(Bromomethyl)-2-fluorobenzenesulphonamide的废液应首先进行中和处理,以降低pH值,避免对环境造成腐蚀性影响。随后...
Loureiriol(CAS号:479195-44-3)的物理化学性质是什么?
Loureiriol是一种天然化合物,其分子式为C15H22O4。Loureiriol为无色结晶性粉末,具有较高的熔点和良好的热稳定性。其相对分子质量为262....
在合成中是否有3-氨基苯甲酰苯胺(CAS号:14315-16-3)的替代品?
在合成过程中,可以考虑使用类似结构的化合物作为3-氨基苯甲酰苯胺的替代品,例如N-苯基-3-氰基苯胺或N-苯基-3-硝基苯胺等,这些化合物具有相似的化学性质,可...
4-异氰酰苯基硼酸频哪醇酯(CAS号:380430-64-8)的市场或研究趋势如何?
4-异氰酰苯基硼酸频哪醇酯主要应用于有机合成、药物化学和材料科学领域。随着绿色化学的发展,该化合物因其高效的官能团转化能力和环境友好性而受到越来越多的关注。近年...
如何储存3β-乙酰氧基-7,25-甘遂二烯-24(R)-醇(CAS号:1352001-09-2)?
3β-乙酰氧基-7,25-甘遂二烯-24(R)-醇应储存在阴凉、干燥、通风良好的地方,避免直接光照。储存容器应密封,防止空气中的水分和氧气影响化合物的稳定性。建...
如何储存4-氟-2-甲基-1H-吲哚(CAS号:1260383-51-4)?
应将4-氟-2-甲基-1H-吲哚存放在阴凉、干燥、通风良好的地方,避免直接暴露在光照下。容器应密封,避免与空气中的水蒸气接触。建议在避光、温度不超过25℃的环境...
来源期刊
Polymer Chemistry

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
![tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure](https://cnstatic.chemtradehub.com/structs/336/336191-16-3-bb55.webp)



