Reply to the ‘Comment on “Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?”’ by I. V. Vasilenko, F. Ganachaud and S. V. Kostjuk, Polym. Chem., 2024, 15, DOI: 10.1039/D3PY00661A

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发布日期 2024-01-03

DOI 10.1039/D3PY01067H

影响因子 5.582

作者

Aurelie Destephen

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摘要

In our previous work we concluded that the Lewis acid-surfactant complex catalyzed polymerization of styrene and other monomers in aqueous dispersed media does not proceed by a cationic polymerization. In a subsequent reply, Vasilenko et al. have suggested that this conclusion is incorrect. Here, we respond to the points raised by Vasilenko et al. and reassert our position that the experimental evidence is more consistent with a radical polymerization than a cationic polymerization and that achieving high molecular weight polymers by a cationic polymerization is not possible in aqueous systems at elevated temperatures unless chain transfer reactions are suppressed.

期刊推荐

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来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Reply to the ‘Comment on “Lewis acid-surfactant complex catalyzed polymerization in aqueous dispersed media: cationic or radical polymerization?”’ by I. V. Vasilenko, F. Ganachaud and S. V. Kostjuk, Polym. Chem., 2024, 15, DOI: 10.1039/D3PY00661A

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