![N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure](https://cnstatic.chemtradehub.com/structs/234/23446-03-9-e1e5.webp "N-{[(2-Methyl-2-propanyl)oxy]carbonyl}-L-methionylglycine structure")
Directed copper-catalyzed dehydrogenative C–H amination of unsaturated sialic acids
文献信息
发布日期
2023-11-27
DOI
10.1039/D3QO01448G
影响因子
5.281
作者
Samir Messaoudi
查看原文
摘要
This study reports the first example of a Cu-catalyzed dehydrogenative C(sp2)–H amination of sialyl glycals. The scope of this reaction is demonstrated by the use of a variety of substituted azole nucleophiles. This approach offers an efficient entry to an unknown chemical space related to N-branched sialyl glycals. Additionally, removal of the directing group and further post functionalizations on the azole nucleus could also be realized by different cross-coupling processes.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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