Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium salts

文献信息

发布日期 2023-11-29

DOI 10.1039/D3QO01719B

影响因子 5.281

作者

Xiao-Di Su, Qing-Shuang Zhang, Bei-Bei Zhang, Lin He, Qiang Liu, Xiang-Yu Chen

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摘要

While aryl sulfonium salts have emerged as a powerful tool for the synthesis of aryl–aryl/CF3 chalcogenides, a general and efficient charge transfer complex (CTC) strategy to access diverse aryl–aryl and aryl–alkyl chalcogenides remains underdeveloped. Herein, we describe a novel photoinduced chalcogen bonding (ChB) approach to synthesize aryl–aryl, aryl–alkyl selenides, and aryl–alkyl sulfides from aryl sulfonium salts. Our experimental and computational studies indicate that ChB facilitates the formation of a photoactive CTC between aryl sulfonium salts and dichalcogenides.

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来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Chalcogen bonding enabled photosynthesis of aryl selenides from aryl sulfonium salts

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