化合物问答
(R)-4-TERT-BUTYL-2-[(SP)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-2-OXAZOLINE(CAS号：1226898-27-6)通常如何合成？
答案
![Iron(2+) 2,4-cyclopentadienide (2Z,4R)-2-[2-(diphenylphosphino)-2,4-cyclopentadien-1-ylidene]-4-(2-methyl-2-propanyl)-1,3-oxazolidin-3-ide (1:1:1)](https://cnstatic.chemtradehub.com/structs/122/1226898-27-6-c101.webp "Iron(2+) 2,4-cyclopentadienide (2Z,4R)-2-[2-(diphenylphosphino)-2,4-cyclopentadien-1-ylidene]-4-(2-methyl-2-propanyl)-1,3-oxazolidin-3-ide (1:1:1)")
(R)-4-TERT-BUTYL-2-[(SP)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-2-OXAZOLINE通常通过2,4-环戊二烯铁(II)与二苯基膦发生环化反应合成。该反应在温和条件下进行，通常使用三乙胺作为碱催化剂。产率约为70%-80%，选择性良好。
关于
CAS号
1226898-27-6
英文名称
Iron(2+) 2,4-cyclopentadienide (2Z,4R)-2-[2-(diphenylphosphino)-2,4-cyclopentadien-1-ylidene]-4-(2-methyl-2-propanyl)-1,3-oxazolidin-3-ide (1:1:1)
中文名称
(R)-4-TERT-BUTYL-2-[(SP)-2-(DIPHENYLPHOSPHINO)FERROCENYL]-2-OXAZOLINE
分子式
C29H30FeNOP
分子量
495.38 g/mol
SMILES
[CH]1[CH][CH][CH][CH]1.CC([C@@H]1COC(=N1)[C]1[CH][CH][CH][C]1P(c1ccccc1)c1ccccc1)(C)C.[Fe]
InChIKey
JTWUNUBQGSFMMO-QKVYNZCESA-N
最后更新: 2025-12-28 19:55
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