化合物问答
二氯[(S)-5,5′-双[二(3,5-二甲苯基)膦]-4,4′-二-1,3-苯并二茂][(1S,2S)-1,2-二苯基乙二胺]钌(II)(CAS号：944450-46-8)通常如何合成？
答案
![[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine](https://cnstatic.chemtradehub.com/structs/944/944450-46-8-769f.webp "[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine")
该化合物通常通过将二氯二(1,2-二苯基乙二胺)钌(II)与二(3,5-二甲苯基)膦在惰性溶剂中进行反应合成。合成过程中需要使用催化剂，如三正丁基锡，以提高产率。该方法的选择性较高，产率可达80%以上。
关于
CAS号
944450-46-8
英文名称
[4-[5-bis(3,5-dimethylphenyl)phosphanyl-1,3-benzodioxol-4-yl]-1,3-benzodioxol-5-yl]-bis(3,5-dimethylphenyl)phosphane;dichlororuthenium;(1S,2S)-1,2-diphenylethane-1,2-diamine
中文名称
二氯[(S)-5,5′-双[二(3,5-二甲苯基)膦]-4,4′-二-1,3-苯并二茂][(1S,2S)-1,2-二苯基乙二胺]钌(II)
分子式
C60H60Cl2N2O4P2Ru
分子量
1107.0739999999998 g/mol
SMILES
CC1=CC(=CC(=C1)P(C2=C(C3=C(C=C2)OCO3)C4=C(C=CC5=C4OCO5)P(C6=CC(=CC(=C6)C)C)C7=CC(=CC(=C7)C)C)C8=CC(=CC(=C8)C)C)C.C1=CC=C(C=C1)C(C(C2=CC=CC=C2)N)N.Cl[Ru]Cl
InChIKey
FOEKPXQPRAIJRW-LISIALKWSA-L
最后更新: 2026-01-01 10:50
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