(3aS)-1-Methyl-3,3-diphenyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole（CAS号：112022-81-8）

(S)-2-甲基-CBS-恶唑硼烷

基本信息

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CAS号

112022-81-8

分子式

C18H20BNO

分子量

277.18 g/mol

化学分类

基础化工原料有机化学品杂环化合物

医药化工医药中间体杂环中间体

基本物理性质

熔点

115-117°C

沸点

111 °C

水溶性

Hydrolyzes in water.

折射率

n20/D 1.460

SMILES

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CB1OC([C@@H]2CCCN12)(c3ccccc3)c4ccccc4

InChI

InChI=1S/C18H20BNO/c1-19-20-14-8-13-17(20)18(21-19,15-9-4-2-5-10-15)16-11-6-3-7-12-16/h2-7,9-12,17H,8,13-14H2,1H3/t17-/m0/s1

InChIKey

VMKAFJQFKBASMU-KRWDZBQOSA-N

LogP

3.5428000000000024

拓扑极性表面积

12.47 Å²

氢键供体/受体

0 / 2

复杂度

344

安全信息

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GHS危险象形图

H315

H319

H335

危险说明

H315 造成皮肤刺激
皮肤腐蚀/刺激

H319 造成严重眼刺激
严重眼损伤/眼刺激

H335 可能造成呼吸道刺激
特定目标器官毒性-单次接触；呼吸道刺激

危险类别

Class 3 Class 3

敏感性

Air & Moisture Sensitive

同义词与引用数据

英文

(S)-Methyl oxazaborolidine
(S)-3,3-Diphenyl-1-methyltetrahydro-3H-pyrrolo[1,2-c][1,3,2]oxazaborole
(S)-2-Methyl-CBS-oxazaborolidine
(S)-3,3-Diphenyl-1-methylpyrrolidino[1,2-c]-1,3,2-oxazaborole
(S)-(-)-2-Methyl-CBS-oxazaborolidine
(S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine
(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in THF
(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1.0 M solution in toluene
(S)-(?)-2-Methyl-CBS-oxazaborolidine
(S)-2-Methyl-CBS-oxazaborolidine (1 M in Toluene)
(S)-2-Methyl-CBS-oxazaborolidine, 1M in toluene
(S)-3,3-Diphenyl-1-Methyltetrahydro-1H,3H-Pyrrolo[1,2-c][1,3,2]Oxazaborole
(S)-Methyl Oxazaborolidine（S-CBS）
(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] (S)-CBS Catalyst
(3aS)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
(S)-(-)-2-Methyl-CBS-oxazaborolidine, 1M solution in toluene
(S)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene
(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole, 0.9-1.1M in toluene [(S)-Methyloxazaborolidine] Corey Catalyst
(S)-Tetrahydro-1-Methyl-3,3-Triphenyl-1H,3H-Pyrrolo[1,2-c][1,3,2]Oxazaborole
(S)-Me-CBS Catalyst
(S)-ME CBS
(s)-methyl
(S)-Tetrahydro-1-Methyl-3
1-(S)-methyl CBS oxazaborolidine
(S)-(+)-Methyl-CBS-oxazaborolidine
(S)-2-Methyl-CBS-oxazaborolidine ,98%
Corey catalyst
(S)-1-Methyl-3,3-diphenylhexahydropyrrolo[1,2-c][1,3,2]oxazaborole
(S)-Methyl-CBS-oxazaborolidine
(S)-Tetrahydro-1-methyl-3,3-diphenyl-1H,3H-pyrrolo[1,2-c][1,3,2]oxazaborole
(S)-METHYL-CBS

中文

(S)-2-甲基-CBS-恶唑硼烷
(S)--2-甲基-CBS-氧杂硼啶
(S)-2-甲基-CBS-氧杂硼啶单水合物
(S)-(+)-甲基-CBS-恶唑硼烷
(S)-甲基恶唑硼烷
(S)-(-)-2-甲基-CBS-噁唑硼烷
(S)-5,5-联苯-2-甲基-3,4-丙醇-1,3,2-恶唑硼烷
(S)-(-)-2-甲基-CBS-噁唑硼烷, 1.0 M 四氢呋喃溶液
(S)-(-)-2-甲基-CBS-噁唑硼烷1M溶液
(S)-2-甲基-CBS-恶唑硼烷甲苯溶液
(S)-2-甲基-CBS-氧杂硼啶
(S)-2-甲基-CBS-氧杂硼啶, 1M 甲苯溶液
(S)-5,5-Diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine (S)-5,5-联苯-2-甲基-3,4-丙醇-1,3,2-恶唑硼烷
(S)-5,5-联苯-2-甲基-3,4-丙醇-1,3,2-恶唑硼烷 (S)-2-甲基-CBS-氧杂硼啶 (S)-2-甲基-CBS-恶唑硼烷
)-(-)-2-甲基-CBS-噁唑硼烷
2-甲基-CBS-氧杂硼啶
S-2-甲基-CBS-恶唑硼烷
α,α-二苯基-L-脯氨醇甲基硼酸环胺酯
(S)-3,3-二苯基-1-甲基四氢-3H-吡咯并[1,2-c][1,3,2]噁唑硼烷
(S)-四氢-1-甲基-3,3-二苯基-1H,3H-吡咯并[1,2-c][1,3,2]噁唑硼烷
(S)-1-甲基-3,3-二苯基-四氢-吡咯并[1,2c][1,3,2]噁唑硼烷