Characterization of different Pt–Ru catalysts by X-ray diffraction and transmission electron microscopy
文献信息
Carbon-supported Pt–Ru (1:1)-catalysts have been synthesized by two reduction methods in an aqueous phase and in a third way in an organic solution and characterized in comparison to a commercial Pt–Ru/C catalyst purchased from E-TEK. X-ray diffraction and transmission electron microscopy were carried out on the different samples in the as-synthesized state and after heat-treatment at 500°C in nitrogen and air atmospheres respectively. Powder patterns of the different catalysts in the as-synthesized state reveal a fcc pattern with d values matching or close to platinum. No evidence of metallic Ru or any oxide phases was found. After heat-treatment in nitrogen Ru reflections occur in the synthesized catalyst samples, backing the supposition of separate platinum and ruthenium particles instead of a Pt–Ru alloy.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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