Two-dimensional diffraction from enantiopure and racemic monolayers of [Ru(bpy)3]2+ intercalated into synthetic fluorohectorite
文献信息
Josef Breu, Alexander Stoll, Kurt G. Lange, Thomas Probst
While for intercalation compounds of natural smectites 2D long range order of the interlamellar space was never observed, in-plane order can be detected using a homogeneously charged synthetic fluorohectorite as host material. With these intercalates distinct 2D structures for enantiopure and racemic [Ru(bpy)3]2+-interlayers, as previously predicted by atomistic simulations, can now be proven experimentally.
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Physical Chemistry Chemical Physics

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