Pyrolysis of organotin compounds: A preparative method for nanometric tin dioxide powders

文献信息

发布日期 2002-08-22
DOI 10.1039/B204476P
影响因子 3.676
作者

A. G. Pereira, A. O. Porto, G. G. Silva, G. M. de Lima, H. G. L. Siebald, J. L. Neto


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摘要

Nanometric tin dioxide powders were obtained by pyrolysis of organotin oxide based compounds such as Sn3O3Bu6 (1) and Sn4O6Bu4 (2) (Bu = n-butyl). The thermal behaviour of 1 and 2 was studied by thermogravimetric analysis (TG) and with simultaneous differential thermal analysis (DTA). Pyrolysis experiments were carried out in three different atmospheres (N2, air and O2) and the residual powders were characterised by X-ray diffraction (XRD) and the morphology was investigated by scanning electron microscopy (SEM). The XRD data showed the formation of pure SnO2 when the decomposition process was accomplished in air or O2, however, in N2, and for Sn4O6Bu4, the X-ray study indicated the formation of a mixture of SnO/SnO2. The micrographs revealed grains of 30–40 nm, approximately.

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来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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