Characterization of binary solvent mixtures: the water–acetonitrile mixture
文献信息
Francisco García-Blanco
Binary mixtures of water and acetonitrile (W/AN) were characterized in the light of the pure solvent scales, using suitable probe/homomorph couples. Various thermodynamic (vapour pressure, softness parameter, excess molar Gibbs energy and enthalpy of mixing) properties, surface tension, viscosity, and spectroscopic (IR, Raman and NMR) properties of the mixtures, and the distribution of molecular structures (viz. free CH3CN and CH3CN–H2O complexes) are described in terms of their polarity, acidity and basicity, and the descriptions examined in relation to a potential physical significance.
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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.














