Stabilisation of an ortho-deprotonated mesityl group within the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate ion
文献信息
Mary McPartlin, Anthony D. Woods, Christopher M. Pask, Thomas Vogler, Dominic S. Wright
The reaction of 2,4,6-Me3C6H2PHNa with Sn(NMe2)2 (3 : 1 equivalents, respectively) results in the formation of the unusual [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]3− stannate trianion in the heterometallic cage [{2,4,6-Me3C6H2P}{4,6-Me2C6H2(2-CH2)P}Sn]Na3·2TMEDA]4 (1), in which unprecedented ortho-Me deprotonation of a [2,4,6-Me3C6H2P]2− ligand has occurred.
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Nature

Pharmacological Reviews

Molecular Pharmacology

Journal of Medicinal Chemistry

Israel Journal of Chemistry

Russian Chemical Reviews

Journal of Physics and Chemistry of Solids

Journal of Organometallic Chemistry

European Journal of Wood and Wood Products

Proceedings of the National Academy of Sciences of the United States of America
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