Regioselective hydroxylation of the xylyl linker in a diiron(iii) complex having a carboxylate-rich ligand with H2O2

文献信息

发布日期 2003-06-25

DOI 10.1039/B304171A

影响因子 6.222

作者

Hideki Furutachi, Mizue Murayama, Amane Shiohara, Satoshi Yamazaki, Shuhei Fujinami, Akira Uehara, Masatatsu Suzuki, Seiji Ogo, Yoshihito Watanabe, Yonezo Maeda

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摘要

Reaction of a diiron(III) complex having a xylta4− ligand (N,N,N′,N′-m-xylylenediamine tetraacetate) with H2O2 resulted in regioselective hydroxylation of the m-xylyl linker. The reaction mimics the self-hydroxylation of a phenylalanine side chain found for ribonucleotide reductase (R2-W48F/D84E).

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Regioselective hydroxylation of the xylyl linker in a diiron(iii) complex having a carboxylate-rich ligand with H2O2

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来源期刊

Chemical Communications

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