An unprecedented mode of ligation for a bridged amido-cyclopentadienide (constrained geometry) ligand; π-olefinic interactions with gallium and indium

文献信息

发布日期 2003-07-10
DOI 10.1039/B304940J
影响因子 6.222
作者

Jeffrey M. Pietryga, Jamie N. Jones, Lucille A. Mullins, Robert J. Wiacek, Alan H. Cowley


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摘要

The surprising reaction of GaCl3 or InBr3 with the di-Grignard reagent [Me2Si(C5Me4)(N-t-Bu)](MgCl)2·THF results in salts of the bimetallic anions of composition [X3M{C5Me4 (N-t-Bu)}MX2]− (M = Ga, X = Cl; M = In; X = Br) in which the MX2 moiety undergoes an η2-interaction with one of the double bonds of the localized cyclopentadienide ring.

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Contents list

Front/Back Matter

DOI: 10.1039/C1CP90214H

Polyureas from diamines and carbon dioxide: synthesis, structures and properties

Haiyang Cheng, Yancun Yu, Zhijian Wu, Dewen Dong, Fengyu Zhao

2011-11-17 Communication

DOI: 10.1039/C1CP23332G

Control of CO2adsorption heats by the Al distribution in FER zeolites

Petr Nachtigall, Lukáš Grajciar, Joaquín Pérez-Pariente, Ana B. Pinar, Arnošt Zukal, Jiří Čejka

2011-12-01 Communication

DOI: 10.1039/C1CP22816A

Where to bind in buckybowls? The dilemma of a metal ion

Hidehiro Sakurai, V. Subramanian, G. Narahari Sastry

2012-01-25 Paper

DOI: 10.1039/C2CP22087C

Infra-red imaging of bulk water and water–solid interfaces under stable and metastable conditions

Lionel Mercury, Paul Dumas

2011-12-22 Paper

DOI: 10.1039/C2CP23221A

Analytical methods for separating and isolating magnetic nanoparticles

Jason R. Stephens, Jacob S. Beveridge, Mary Elizabeth Williams

2012-02-03 Perspective

DOI: 10.1039/C2CP22982J

The adsorption of quinizarin on boron-doped diamond

Ivan B. Dimov, Christopher Batchelor-McAuley, Leigh Aldous, Richard G. Compton

2011-12-14 Paper

DOI: 10.1039/C2CP23380K

Understanding solvent effects in the selective conversion of fructose to 5-hydroxymethyl-furfural: a molecular dynamics investigation

Samir H. Mushrif, Stavros Caratzoulas, Dionisios G. Vlachos

2012-01-25 Paper

DOI: 10.1039/C2CP22694D

Cation interdiffusion model for enhanced oxygen kinetics at oxide heterostructure interfaces

Milind J. Gadre, Yueh-Lin Lee

2012-01-23 Paper

DOI: 10.1039/C2CP23033J

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来源期刊

Chemical Communications

Chemical Communications
CiteScore: 8.6
自引率: 4.7%
年发文量: 2458

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