Concise total synthesis of the aporphine alkaloid 7,7′-bisdehydro-O-methylisopiline by an InCl3 mediated cycloisomerization reaction
文献信息
Alois Fürstner, Victor Mamane
A novel InCl3 mediated cycloisomerization reaction leading to 10-halophenanthrene derivatives constitutes the key step of the first total syntheses of O-methyldehydroisopiline 10 and 7,7′-bisdehydro-O-methylisopiline 11, two prototype members of the aporphine family of alkaloids.
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Chemical Communications

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