Oxygenation of thiolates to S-bonded sulfinate in an iron(iii) complex related to nitrile hydratase

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发布日期 2003-12-16

DOI 10.1039/B312318A

影响因子 6.222

作者

Erwan Galardon, Michel Giorgi, Isabelle Artaud

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摘要

Air oxidation of the iron(III) complex derived from (2-mercaptoisobutyryl)-4,5-dichloro-o-phenylenediamine in the presence of Et4NCN afforded the corresponding disulfinato species. With two carboxamido nitrogens trans to two S-bonded sulfinates, this complex mimics the disulfinate inactive form of Fe-NHase.

期刊推荐

NDT & E International

Main Group Chemistry

Colloid Journal

Critical Reviews in Solid State and Materials Sciences

Bioorganic & Medicinal Chemistry Letters

Chinese Journal of Chemistry

Bioorganic & Medicinal Chemistry

Atomization and Sprays

Herald of the Russian Academy of Sciences

Acta Metallurgica Sinica-English Letters

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Oxygenation of thiolates to S-bonded sulfinate in an iron(iii) complex related to nitrile hydratase

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