High-efficiency and minimum-waste continuous kinetic resolution of racemic alcohols by using lipase in supercritical carbon dioxide
文献信息
发布日期
2004-08-26
DOI
10.1039/B406882C
影响因子
6.222
作者
Tomoko Matsuda, Kazunori Watanabe, Tadao Harada, Kaoru Nakamura, Yoshitaka Arita, Yukihiro Misumi, Shinichiro Ichikawa, Takao Ikariya
查看原文
摘要
A novel continuous-flow scCO2 process for kinetic resolution of racemic alcohols can be performed with an immobilized lipase to lead to a quantitative mixture of the corresponding optically active acetates with up to 99% ee and unreacted alcohols with up to 99% ee, in which the productivity of the optically active compounds was improved by over 400 times compared to the corresponding batch reaction using scCO2.
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来源期刊
Chemical Communications
CiteScore:
8.6
自引率:
4.7%
年发文量:
2458
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