An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated “phosphaamidinate” anion

文献信息

发布日期 2004-09-28

DOI 10.1039/B408994D

影响因子 6.222

作者

René T. Boeré, Marcus L. Cole, Peter C. Junk, Jason D. Masuda, Gotthelf Wolmershäuser

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摘要

The reaction of DippPH2 (Dipp = 2,6-iPr2C6H3) with DippNC(p-CH3C6H4)Cl in refluxing xylenes affords DippPC(p-CH3C6H4)N(H)Dipp; deprotonation with alkali metal reagents produces unique lithium and potassium complexes with the ligand in a different geometry to that of the free phosphaamidine.

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Photochemical & Photobiological Sciences

Molecular Diversity

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Mini-Reviews in Medicinal Chemistry

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Angewandte Chemie International Edition

Foundations of Chemistry

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Advanced Engineering Materials

来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

An N,P-disubstituted-2-aminophosphaalkene and lithium and potassium complexes of the deprotonated “phosphaamidinate” anion

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推荐化合物

Methyl 2-amino-4-bromobenzoate

(1S,2R,4S)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-ol

3-(Diethylamino)-1,2-propanediol

Gadolinium chloride (GdCl3)

2,5-Furandione, dihydro-3-[3-(triethoxysilyl)propyl]-

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