Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(μ3-O)8 core

文献信息

发布日期 2005-05-31

DOI 10.1039/B503830H

影响因子 6.222

作者

Jean-Claude Berthet, Pierre Thuéry, Michel Ephritikhine

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摘要

The smooth comproportionation reaction of the U(VI) and U(III) complexes UO2(OTf)2 and U(OTf)3, afforded the hexanuclear U(IV) oxide cluster [U6(μ3-O)8(μ2-OTf)8(py)8], a rare example of a metal oxide with a M6(μ3-O)8 core.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Unprecedented reduction of the uranyl ion [UO2]2+ into a polyoxo uranium(iv) cluster: Synthesis and crystal structure of the first f-element oxide with a M6(μ3-O)8 core

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