Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}
文献信息
Anupama Ranganathan, Abdelkrim El-Ghayoury, Cécile Mézière, Etienne Harté, Rodolphe Clérac, Patrick Batail
The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic–inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.
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Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














