Competitive O–H and C–H oxidative addition of CH3OH to rhodium(ii) porphyrins
文献信息
Shan Li, Weihong Cui, Bradford B. Wayland
Rhodium(II) porphyrins react with CH3OH in benzene by alternate mechanisms that give H–CH2OH and H–OCH3 bond activation in different methanol concentration regimes which is a rare example of transition metal reactivity with methanol.
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来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry












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