Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source
文献信息
Jeremiah D. Harden, Joshua V. Ruppel, Guang-Yao Gao, X. Peter Zhang
Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.
相关文献
The crystal structure and chemical state of aluminum-doped hydroxyapatite by experimental and first principles calculation studies
Ming Wang, Liping Wang, Chao Shi, Tian Sun, Yingchun Zhu
DOI: 10.1039/C6CP03230C
Effects of halogen doping on nanocarbon catalysts synthesized by a solution plasma process for the oxygen reduction reaction
Yuta Wada, Satoshi Chiba, Sou Kumagai, Hoonseung Lee, Ai Serizawa, Oi Lun Li, Gasidit Panomsuwan
DOI: 10.1039/C6CP03579E
Molecular weight growth in Titan's atmosphere: branching pathways for the reaction of 1-propynyl radical (H3CCC˙) with small alkenes and alkynes
Benjamin B. Kirk, John D. Savee, Adam J. Trevitt, David L. Osborn, Kevin R. Wilson
DOI: 10.1039/C5CP02589C
Is formamide a geochemically plausible prebiotic solvent?
Jeffrey L. Bada, John H. Chalmers
DOI: 10.1039/C6CP03290G
Comparing the catalytic strategy of ATP hydrolysis in biomolecular motors
Stefan Fischer
DOI: 10.1039/C6CP01364C
Triple decker sandwiches and related compounds of the first row transition metals with cyclopentadienyl and hexafluorobenzene rings: remarkable effects of fluorine substitution
Shida Gong, Qiong Luo, Xiangfei Feng, Qian-shu Li, Yaoming Xie, Henry F. Schaefer III
DOI: 10.1039/C5CP01648G
Cysteine containing dipeptides show a metal specificity that matches the composition of seawater
Luca Belmonte, Daniele Rossetto, Michele Forlin, Simone Scintilla, Claudia Bonfio, Sheref S. Mansy
DOI: 10.1039/C6CP00608F
A symbiotic view of the origin of life at hydrothermal impact crater-lakes
DOI: 10.1039/C6CP00550K
A unified diabatic description for electron transfer reactions, isomerization reactions, proton transfer reactions, and aromaticity
Ross H. McKenzie
DOI: 10.1039/C5CP02236C
您可能还喜欢
如何处理含有3-氯苯甲酰肼(CAS号:1673-47-8)的废料?
处理含有3-氯苯甲酰肼(CAS号:1673-47-8)的废料时,应首先收集并分类,确保废液中不含有其他有害物质。然后,采用适当的化学方法进行处理,如生物降解或化...
(2E)-N-(2-氨基-4-氟苯基)-3-[1-(3-苯基-2-丙烯-1-基)-1H-吡唑-4-基]-2-丙烯酰胺(CAS号:1396841-57-8)应用于哪些行业?
(2E)-N-(2-氨基-4-氟苯基)-3-[1-(3-苯基-2-丙烯-1-基)-1H-吡唑-4-基]-2-丙烯酰胺主要应用于医药行业,作为药物前体或中间体。此...
什么是对-N,N-二甲氨基苯甲酸乙酯(CAS号:10287-53-3)?
对-N,N-二甲氨基苯甲酸乙酯是一种有机化合物,化学式为C10H14N2O2,分子量为202.23。其结构由苯甲酸乙酯基团与对位连接的N,N-二甲氨基取代基组成...
3,6-二溴-9-(4-甲基苯基)-9H-咔唑(CAS号:357437-74-2)的物理化学性质是什么?
3,6-二溴-9-(4-甲基苯基)-9H-咔唑是一种深红色固体,具有较高的结晶性。其分子量约为416.25 g/mol。该化合物易溶于有机溶剂如DMF、DMSO...
在合成中是否有FMOC-(2R,4S)-PRO(4-F)-OH(CAS号:913820-87-8)的替代品?
在合成中,可以考虑使用类似结构的化合物作为替代品,例如FMOC-(2R,4R)-PRO(4-F)-OH。这些替代品在结构上类似,可以用于类似的化学反应中。不过,...
2-苄基八氢环戊并[c]吡咯-4-胺(CAS号:186201-60-5)的主要用途是什么?
2-苄基八氢环戊并[c]吡咯-4-胺主要用于有机合成和药物化学研究领域,作为合成中间体或先导化合物。此外,由于其独特的化学结构,它也可能在某些特定的医药应用中发...
奥氮平N乙酰基杂质(CAS号:935272-10-9)的市场或研究趋势如何?
奥氮平N乙酰基杂质的市场趋势主要集中在药物生产和研究领域。随着奥氮平及其类似药物在临床上的应用越来越广泛,对相关杂质的研究和控制也愈加重视。近年来,研究人员更关...
处理Chloropropylate(CAS号:5836-10-2)时应注意哪些实验室安全事项?
在处理氯丙基酯(Chloropropylate)时,应注意以下安全事项:1. 佩戴适当的个人防护装备,包括防护眼镜、实验室外套和手套。2. 在通风橱中进行操作,...
在合成中是否有4-氢氯化氨基安替比林(CAS号:22198-72-7)的替代品?
在合成中,可以考虑使用4-氨基安替比林作为原料,通过不同的合成路线制备4-氢氯化氨基安替比林。此外,也可以探索其他含有氨基和氯化基团的化合物作为潜在替代品。
如何处理含有3-脱氧-D-葡糖酮醛(CAS号:4084-27-9)的废料?
处理含有3-脱氧-D-葡糖酮醛的废料时,首先应确保废液收集于合适的容器中,并密封好。随后,可以考虑采用焚烧或交由专业废弃物处理公司进行处理的方法。在处理过程中,...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![[2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure [2-(Benzyloxy)-3-bromo-5-methylphenyl]boronic acid structure](https://cnstatic.chemtradehub.com/structs/870/870777-20-1-24ac.webp)

![4-[(1-Methyl-1H-pyrrol-2-yl)methylene]-1,3(2H,4H)-isoquinolinedione structure 4-[(1-Methyl-1H-pyrrol-2-yl)methylene]-1,3(2H,4H)-isoquinolinedione structure](https://cnstatic.chemtradehub.com/structs/110/1104546-89-5-a600.webp)
![2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole structure 2-(Methylsulfonyl)-2,4,5,6-tetrahydropyrrolo[3,4-c]pyrazole structure](https://cnstatic.chemtradehub.com/structs/122/1226781-80-1-09d5.webp)