Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
文献信息
Luca Ronconi
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.
相关文献
Molecular structures of M2N22− (M and N = B, Al, and Ga) clusters using the gradient embedded genetic algorithm
Jordi Poater, Eduard Matito, Miquel Solà
DOI: 10.1039/C2CP42210G
Contrasting preferences of N and P substituted heteroaromatics towards metal binding: probing the regioselectivity of Li+ and Mg2+ binding to (CH)6−m−nNmPn
Bhaskar Sharma, Deivasigamani Umadevi, G. Narahari Sastry
DOI: 10.1039/C2CP41834G
Structure, spectroscopy and dynamics of layered H2O and CO2 ices
Myung Won Lee, Nuria Plattner, Markus Meuwly
DOI: 10.1039/C2CP41904A
Graphene on metallic surfaces: problems and perspectives
Elena Voloshina, Yuriy Dedkov
DOI: 10.1039/C2CP42171B
Thermal decomposition of solution processable metal xanthates on mesoporous titanium dioxide films: a new route to quantum-dot sensitised heterojunctions
Thierry Lutz, Andrew MacLachlan, Anna Sudlow, Jenny Nelson, Michael S. Hill, Saif A. Haque
DOI: 10.1039/C2CP43534A
New insights into the mechanism of electron transfer within flavohemoglobins: tunnelling pathways, packing density, thermodynamic and kinetic analyses
Emna El Hammi, Chantal Houée-Lévin, Jan Řezáč, Bernard Lévy, Isabelle Demachy, Laura Baciou, Aurélien de la Lande
DOI: 10.1039/C2CP41261F
Catalytic activity of Co–Nx/C electrocatalysts for oxygen reduction reaction: a density functional theory study
Shyam Kattel, Plamen Atanassov, Boris Kiefer
DOI: 10.1039/C2CP42609A
Electronic fluxes during large amplitude vibrations of single, double and triple bonds
Timm Bredtmann, Beate Paulus
DOI: 10.1039/C2CP42494K
Composite fuelelectrode La0.2Sr0.8TiO3−δ–Ce0.8Sm0.2O2−δ for electrolysis of CO2 in an oxygen-ion conducting solid oxide electrolyser
Yuanxin Li, Jianer Zhou, Dehua Dong, Yan Wang, J. Z. Jiang, Hongfa Xiang
DOI: 10.1039/C2CP42232H
您可能还喜欢
如何储存8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯(CAS号:1072944-81-0)?
8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯应储存在阴凉、干燥的地方,避免光照和高温。建议使用密封容器进行储存,以防止水分和空气的影响。
2,2-二(2-呋喃基)丙烷(CAS号:17920-88-6)的市场或研究趋势如何?
2,2-二(2-呋喃基)丙烷的研究趋势主要集中在新型材料的开发和应用,如高分子材料、有机光电材料等。市场趋势方面,随着环保要求的提高和新材料的应用,该化合物的需...
如何处理含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐(CAS号:475152-31-9)的废料?
对于含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐的废料,应首先进行分类和分离,以减少危险物质的数量。随后,可以考虑通过化学氧化、生物...
Cinnamyl 3-aminobut-2-enoate(CAS号:113898-97-8)安全吗?
Cinnamyl 3-氨基丁-2-烯酸在接触皮肤和眼睛时可能会引起刺激。应避免吸入其粉尘和烟雾。操作时应穿戴适当的个人防护装备,如手套、护目镜和实验室外套。
反式-2-十二碳烯二酸(CAS号:6402-36-4)的市场或研究趋势如何?
反式-2-十二碳烯二酸在医药、材料科学等领域有一定的应用,但其市场相对较小。近年来,由于环保意识的提升,对环境友好型化学品的需求增加,研究倾向于开发更绿色的合成...
什么是(9ci)-1H-苯并咪唑-5-乙酸(CAS号:473895-86-2)?
(9ci)-1H-苯并咪唑-5-乙酸是一种含氮杂环化合物,其化学结构为1H-苯并咪唑-5-乙酸。该化合物具有特定的分子式C8H7NO2,属于有机酸类化合物。
酞菁蓝(CAS号:147-14-8)的主要用途是什么?
酞菁蓝主要用作颜料和染料,广泛应用于塑料、油墨、涂料、纺织品及橡胶工业中。它也用于光敏材料,如太阳能电池和光刻胶。在医疗领域,酞菁蓝因其光敏特性被用于某些光动力...
5-甲基-1,2,3,4-四氢异喹啉(CAS号:123593-99-7)安全吗?
5-甲基-1,2,3,4-四氢异喹啉在使用和储存时需要谨慎处理。它具有一定的毒性,应避免吸入其蒸气或直接接触皮肤和眼睛。操作此化合物时,建议佩戴防护眼镜、实验服...
如何处理含有3',4',5'-三甲氧基苯乙酮(CAS号:1136-86-3)的废料?
含有3',4',5'-三甲氧基苯乙酮的废液应首先确保其是否为危险废物,根据当地法规确定处理方法。通常,这类有机废液可以采用中和反应降低其pH值,然后通过蒸馏或萃...
如何储存KI-7(CAS号:1489263-00-4)?
KI-7应储存在通风良好的干燥环境中,避免光照和高温。建议使用密封容器储存,并保持在阴凉处。储存温度应控制在室温范围内,一般建议不超过25°C。避免与氧化剂接触...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry











![2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure 2,4-Dichloro-6-isopropyl-5H-pyrrolo[3,4-d]pyrimidin-7(6H)-one structure](https://cnstatic.chemtradehub.com/structs/107/1079649-94-7-ad4a.webp)


