Univalent transition metal complexes of arenes stabilized by a bulky terphenylligand: differences in the stability of Cr(i), Mn(i) or Fe(i) complexes

文献信息

发布日期 2007-12-20

DOI 10.1039/B715027J

影响因子 6.222

作者

Chengbao Ni, Bobby D. Ellis, James C. Fettinger, Gary J. Long, Philip P. Power

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摘要

Two univalent transition metal complexes, (µ-η6:η6-C7H8){MnAr*-3,5-Pri2}2 (1) and (η6-C6H6)FeAr*-3,5-Pri2 (2) (Ar*-3,5-Pri2 = C6H-2,6-(C6H2-2,4,6-Pri3)2-3,5-Pri2), that have η6 arene coordination were synthesized by reduction of the corresponding metal halides. The complexes are thermally stable in contrast to the corresponding Cr(I) complexes of benzene or toluene which decompose at room temperature.

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来源期刊

Chemical Communications

CiteScore: 8.6

自引率: 4.7%

年发文量: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Univalent transition metal complexes of arenes stabilized by a bulky terphenylligand: differences in the stability of Cr(i), Mn(i) or Fe(i) complexes

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来源期刊

Chemical Communications

推荐化合物

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