Recent advancements and challenges of palladiumII-catalyzed oxidation reactions with molecular oxygen as the sole oxidant
文献信息
Keith M. Gligorich, Matthew S. Sigman
During the past 10 years there have been significant advances in PdII-catalyzed oxidation reactions where the use of ligands has led to the development of catalytic systems capable of achieving high turnover numbers, which employ molecular oxygen as the sole stoichiometric oxidant. This Feature article will highlight some of the recent developments in direct molecular oxygen-coupled PdII-catalyzed oxidation reactions with an emphasis on enhanced catalytic systems and new reactions. Additionally, limitations of current catalytic systems, such as ligand oxidation, are presented and their implications for the development of new reactions are discussed.
相关文献
CCSD(T) level interaction energy for halogen bond between pyridine and substituted iodobenzenes: origin and additivity of substituent effects
Seiji Tsuzuki, Tadafumi Uchimaru, Akihiro Wakisaka, Taizo Ono, Takaaki Sonoda
DOI: 10.1039/C3CP43693D
A model theoretical study on ligand exchange reactions of CooA
Toshimasa Ishida, Shigetoshi Aono
DOI: 10.1039/C3CP43253J
Water and ammonia on Cu{110}: comparative structure and bonding
Stephen J. Jenkins
DOI: 10.1039/C3CP42658K
Mechanism of morphology transformation during annealing of nanostructured gold films on glass
Tanya Karakouz, Alexander B. Tesler, Takumi Sannomiya, Yishay Feldman, Alexander Vaskevich, Israel Rubinstein
DOI: 10.1039/C3CP50198A
Impact of long-range van der Waals forces on chiral recognition in a Cinchona alkaloid chiral selector system
Petr Milko, Jana Roithová, Kevin A. Schug, Karel Lemr
DOI: 10.1039/C3CP44444A
A polarizable embedding DFT study of one-photon absorption in fluorescent proteins
Maarten T. P. Beerepoot, Arnfinn Hykkerud Steindal, Jacob Kongsted, Bjørn Olav Brandsdal, Luca Frediani, Kenneth Ruud, Jógvan Magnus Haugaard Olsen
DOI: 10.1039/C3CP44659J
Anisotropy of the water–carbon interaction: molecular simulations of water in low-diameter carbon nanotubes
Guillermo Pérez-Hernández, Burkhard Schmidt
DOI: 10.1039/C3CP44278K
TiO2nanowire electron transport pathways inside organic photovoltaics
Pinyi Yang, Diane K. Zhong, Mingjian Yuan, Andrew H. Rice, Daniel R. Gamelin, Christine K. Luscombe
DOI: 10.1039/C3CP50325A
您可能还喜欢
什么是5-Fluoro-4-iodo-2-methylaniline(CAS号:307306-08-7)?
5-氟-4-碘-2-甲氨基苯属于芳香族化合物,其分子式为C8H7FN2I。该化合物具有一定的反应活性,在有机合成和药物化学领域有一定的应用。
4-氟-3-硝基三氟甲苯(CAS号:367-86-2)通常如何合成?
4-氟-3-硝基三氟甲苯通常通过将三氟甲基苯在酸性条件下催化氧化为三氟甲基硝基苯,然后进行氟化反应得到目标化合物。该过程需要使用催化剂,如三氟乙酸,反应产率较高...
6-氯-9-(2,3,5-三苯甲酰氧基-2-C-甲基-beta-D-呋喃核糖基)-9H-嘌呤(CAS号:205171-05-7)的物理化学性质是什么?
该化合物为白色至类白色晶体,分子量约为1046.95。它在水中几乎不溶,在有机溶剂如乙腈和甲醇中具有一定的溶解性。该化合物具有良好的化学稳定性和生物活性。
如何储存6-氟喹啉-4-羧酸(CAS号:220844-73-5)?
6-氟喹啉-4-羧酸应储存在阴凉、干燥、通风良好的地方,避免阳光直射。储存在密闭容器中,避免与空气中的水分接触。储存温度应控制在室温以下,避免高温。
(2S,2'S,3S,3'S)-3,3'-di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole(CAS号:1435940-21-8)通常如何合成?
该化合物通常通过芳香族化合物的亲核取代反应合成,首先将2,6-二甲氧基苯基引入到双环结构中,然后通过特定条件下的还原或氧化反应引入二叔丁基。反应过程中使用了钯作...
如何储存KY02111(CAS号:1118807-13-8)?
KY02111应储存于阴凉、干燥、通风良好的地方,避免阳光直射和高温环境。应使用合适的密闭容器储存,并确保容器密封良好,防止水分和潮气进入。在储存期间,应注意检...
如何储存4-(4-氯苯氧基)丁酸乙酯(CAS号:59227-79-1)?
4-(4-氯苯氧基)丁酸乙酯应储存在阴凉、干燥、通风良好的地方,远离火源和热源。避免阳光直射,防止容器破裂导致泄漏。储存时应保持容器密封,避免与空气中的水蒸气接...
4-庚基苯乙酮(CAS号:37593-03-6)安全吗?
4-庚基苯乙酮相对安全,但在使用和储存时仍需注意。应避免吸入其蒸气,避免皮肤接触,使用时需佩戴防护眼镜和手套。储存时应远离火源和热源,保持容器密封,放置于阴凉、...
什么是乙基2-氨基-4-(3-溴苯基)噻吩-3-羧酸乙酯(CAS号:438218-48-5)?
乙基2-氨基-4-(3-溴苯基)噻吩-3-羧酸乙酯是一种有机化合物,分子式为C16H12BrN2O2S。它是一种含有噻吩环、氨基、溴苯基和羧酸酯结构的化合物。这...
什么是(9ci)-2-氨基-6-甲基-苯甲酰胺(CAS号:1885-31-0)?
(9ci)-2-氨基-6-甲基-苯甲酰胺是一种化学化合物,其英文名称为2-Amino-6-methylbenzamide,CAS号为1885-31-0。该化合物...
来源期刊
Chemical Communications

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry














