Ionicity in ionic liquids: correlation with ionic structure and physicochemical properties
文献信息
Kazuhide Ueno, Hiroyuki Tokuda, Masayoshi Watanabe
Ionic liquids (ILs) are ambient temperature molten salts that have attracted considerable attention because of their negligible volatility, thermal stability, nonflammability, and high ionic conductivity. These remarkable properties result essentially from their ionic nature. Thus, the concept of ionicity of ILs (i.e. how ionic they are) is of great significance for characterising their properties. Here, we show the methodologies used to assess the ionic nature in ILs. On the basis of quantitative estimation of the ionicity, their dependence on ionic structure, polarity scales, and physicochemical properties is reviewed. The ionicity of certain ILs is also predicted from their physicochemical properties. The effects of different classes of ILs (e.g., protic ILs and lithium ILs) and binary systems consisting of ILs and other components on the ionicity are also discussed.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











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