Catalysis by metal–organic frameworks: fundamentals and opportunities

文献信息

发布日期 2011-01-14
DOI 10.1039/C0CP02394A
影响因子 3.676
作者

Marco Ranocchiari


查看原文

摘要

Crystalline porous materials are extremely important for developing catalytic systems with high scientific and industrial impact. Metal–organic frameworks (MOFs) show unique potential that still has to be fully exploited. This perspective summarizes the properties of MOFs with the aim to understand what are possible approaches to catalysis with these materials. We categorize three classes of MOF catalysts: (1) those with active site on the framework, (2) those with encapsulated active species, and (3) those with active sites attached through post-synthetic modification. We identify the tunable porosity, the ability to fine tune the structure of the active site and its environment, the presence of multiple active sites, and the opportunity to synthesize structures in which key–lock bonding of substrates occurs as the characteristics that distinguish MOFs from other materials. We experience a unique opportunity to imagine and design heterogeneous catalysts, which might catalyze reactions previously thought impossible.

相关文献

Effect of sodium salicylate and sodium deoxycholate on fibrillation of bovine serum albumin: comparison of fluorescence, SANS and DLS techniques

J. Dey, S. Kumar, V. K. Aswal, L. V. Panicker, K. Ismail, P. A. Hassan

2015-05-12 Paper

DOI: 10.1039/C5CP01666E

Molecular diffusion and dc conductivity perfectly correlated with molecular rotational dynamics in a plastic crystalline electrolyte

M. Zachariah, M. Romanini, P. Tripathi, J. Ll. Tamarit, R. Macovez

2015-05-20 Paper

DOI: 10.1039/C5CP02345A

Towards an ab initio description of the optical spectra of light-harvesting antennae: application to the CP29 complex of photosystem II

Sandro Jurinovich, Lucas Viani, Ingrid G. Prandi, Thomas Renger, Benedetta Mennucci

2015-04-01 Paper

DOI: 10.1039/C4CP05647G

Low-temperature VUV photoluminescence and thermoluminescence of UV excited afterglow phosphor Sr3AlxSi1−xO5:Ce3+,Ln3+ (Ln = Er, Nd, Sm, Dy and Tm)

Hongde Luo, Adrie J. J. Bos, Anna Dobrowolska, Pieter Dorenbos

2015-05-13 Paper

DOI: 10.1039/C5CP01710F

Enhanced photocurrent density of hematite thin films on FTO substrates: effect of post-annealing temperature

Eun Soo Cho, Myung Jong Kang, Young Soo Kang

2015-05-26 Paper

DOI: 10.1039/C5CP01823D

Electronic couplings for molecular charge transfer: benchmarking CDFT, FODFT and FODFTB against high-level ab initio calculations. II

Adam Kubas, Fruzsina Gajdos, Harald Oberhofer, Jochen Blumberger

2014-12-22 Paper

DOI: 10.1039/C4CP04749D

Conjugated polymer P3HT–Au hybrid nanostructures for enhancing photocatalytic activity

Bikash Jana, Santanu Bhattacharyya, Amitava Patra

2015-05-19 Paper

DOI: 10.1039/C5CP01769F

您可能还喜欢

化合物问答

N-2,2-丙烯基-2-丙烯酰胺(CAS号:2555-13-7)通常如何合成?

N-2,2-丙烯基-2-丙烯酰胺通常通过丙烯酰胺与丙烯基卤化物的缩合反应合成。该反应通常在温和的条件下进行,使用适量的碱如吡啶作为催化剂。反应的选择性良好,产率...

2555-13-7N-Allylacrylamide
化合物问答

什么是1,2-二碘四氟代乙烷(CAS号:354-65-4)?

1,2-二碘四氟代乙烷是一种有机化合物,化学式为C2F4I2,CAS号为354-65-4。它是一种无色透明液体,具有特殊的化学性质和物理性质,包括高沸点、低挥发...

354-65-41,1,2,2-Tetrafluoro-...
化合物问答

3-溴-1H-吡咯[3,2-c]吡啶-4-碳腈(CAS号:1000341-71-8)适用哪些法规指南?

根据GHS(全球化学品统一分类和标签制度),3-溴-1H-吡咯[3,2-c]吡啶-4-碳腈被归类为第2类易燃液体。在欧盟,该化合物需要符合REACH法规的要求,...

1000341-71-83-Bromo-1H-pyrrolo[3...
化合物问答

1-氯甲基萘磺酸(CAS号:87491-79-0)安全吗?

1-氯甲基萘磺酸在使用时需要谨慎,因为它具有一定的刺激性和腐蚀性。操作时应佩戴适当的防护装备,如防化服、手套、护目镜等,避免直接接触皮肤和吸入其蒸汽。

87491-79-01-((Chloromethyl)sul...
化合物问答

二氯(二环戊二烯)铂(CAS号:12083-92-0)的主要用途是什么?

该化合物主要用于催化剂领域,特别是在有机合成中的催化氧化反应以及作为某些药物合成的中间体。此外,它还被研究用于纳米材料的制备。

12083-92-0(1S,7R)-Tricyclo[5.2...
化合物问答

3-溴-7-氯噻吩并[3,2-b]吡啶-6-甲腈(CAS号:798574-82-0)安全吗?

3-溴-7-氯噻吩并[3,2-b]吡啶-6-甲腈在处理时需要谨慎,因其含有溴和氯等强卤素,可能具有一定的刺激性和腐蚀性。使用时应佩戴适当的个人防护装备,避免皮肤...

798574-82-03-Bromo-7-chlorothie...
化合物问答

(R)-1-((R)-2-(2’-二环己基膦苯基)三戊铁基]乙基(双-3,5-三氟甲基苯基)膦(CAS号:494227-32-6)的主要用途是什么?

该化合物主要用于有机合成领域,特别是作为催化剂或配体,在有机合成反应中发挥重要作用。此外,它还可能应用于催化加氢反应、偶联反应等。

494227-32-6Walphos SL-W008-1
化合物问答

3-[6-(Diphenylphosphoryl)-2-naphthyl]-1,10-phenanthroline(CAS号:1480371-38-7)安全吗?

3-[6-(Diphenylphosphoryl)-2-naphthyl]-1,10-phenanthroline在正常使用条件下相对安全,但在操作时应穿戴适当...

1480371-38-73-[6-(Diphenylphosph...
化合物问答

在合成中是否有ETHYL 2-(4-(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)CYCLOHEX-3-ENYL)ACETATE(CAS号:1166829-70-4)的替代品?

可以考虑使用类似结构的化合物作为替代品,如2-(4-环戊基环己烯基)乙酸酯,这种化合物在结构上相似,可能在某些合成路径中作为替代品。

1166829-70-4Ethyl [4-(4,4,5,5-te...
化合物问答

如何处理含有3-(3-氨基丙基)丙酮缩甘油(CAS号:131606-42-3)的废料?

处理含有3-(3-氨基丙基)丙酮缩甘油的废料时,首先应确保遵守当地的环保法规。对于危险废物,应进行分类收集,然后送至专业的废物处理设施进行焚烧或安全填埋。在处理...

131606-42-33-[(2,2-Dimethyl-1,3...

来源期刊

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
自引率: 10.3%
年发文量: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

推荐供应商

免责声明
本页面提供的学术期刊信息仅供参考和研究使用。我们与任何期刊出版商均无关联,也不处理投稿事宜。如有投稿相关咨询,请直接联系相关期刊出版商。
如发现页面信息有误,请发送邮件至 support@chemtradehub.com 联系我们。我们将及时核实并处理您的问题。