Near-critical water, a cleaner solvent for the synthesis of a metal–organic framework
文献信息
Ilich A. Ibarra, Peter A. Bayliss, Eduardo Pérez, Sihai Yang, Alexander J. Blake, Harriott Nowell, David R. Allan, Martyn Poliakoff, Martin Schröder
The microporous metal–organic framework {[Zn2(L)]·(H2O)3}∞ (H4L = 1,2,4,5-tetrakis(4-carboxyphenyl)benzene) has been synthesised using near-critical water (300 °C) as a cleaner alternative to toxic organic solvents. A single crystal X-ray structure determination confirms that the complex incorporates tetrahedral Zn(II) centres bridged through the carboxylate anions to form a binuclear building block, which extends into a one dimensional chain along the c axis. Four L4− ligands bind to each Zn(II) centre and cross-link the one dimensional chains along both a and b axes to afford a three dimensional network structure incorporating pores of ca. 4.3 Å in diameter. The complex shows high thermal stability up to 425 °C by gravimetric thermal analysis, and on desolvation, displays a high adsorption enthalpy of 11.0 kJ mol−1 for H2 uptake at zero coverage, consistent with the narrow pore diameter for the framework.
期刊推荐

Chemistry of Natural Compounds

Bulletin of the Chemical Society of Japan

Journal of the American Chemical Society

Anti-Corrosion Methods and Materials

Australian Journal of Chemistry

Accounts of Chemical Research

Chemistry of Heterocyclic Compounds

Doklady Chemistry

Chemical & Pharmaceutical Bulletin

Cement and Concrete Research
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