N-Heterocyclic carbenesversus transition metals for stabilizing phosphinyl radicals

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发布日期 2011-02-18

DOI 10.1039/C1SC00027F

影响因子 9.825

作者

Olivier Back, Bruno Donnadieu, Moritz von Hopffgarten, Susanne Klein, Ralf Tonner, Gernot Frenking, Guy Bertrand

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摘要

It is shown that vanadium-iminato ligands are more efficient than imidazolidin-2-iminato substituents to delocalize the spin density from a phosphorus nucleus. However, the latter is stabilizing enough to allow for the isolation and characterization in the liquid and solid states of a neutral phosphinyl radical.

期刊推荐

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Letters in Organic Chemistry

来源期刊

Chemical Science

CiteScore: 14.4

自引率: 3.9%

年发文量: 1413

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N-Heterocyclic carbenesversus transition metals for stabilizing phosphinyl radicals

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来源期刊

Chemical Science

推荐化合物

1-Benzofuran-6-carboxylic acid

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3-Bromo-9H-carbazole

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