Facile growth of silver crystals with greatly varied morphologies by PEO-PPO-PEO tri-block copolymers
文献信息
Jing-Cyuan Yang, Chun-Hua Chen, Ren-Jye Wu
Silver crystals with various novel nano-scale morphologies were synthesized from the reduction of silver nitrate (AgNO3) by ascorbic acid (AsA) in aqueous PEO-PPO-PEO tri-block copolymer (F127) solutions. The presence of only high-concentration AsA at the very initial stage of reduction acts as a key factor in forming distinct branched quasi-spherical Ag nanocrystals where coral-like and houseleek-like morphologies can be kinetically controlled via subsequent addition of F127. When AsA and F127 were mixed before the reduction, three-dimensional dendritic Ag nanocrystals with highly ordered dendrites were largely obtained. In contrast to these branched crystals prepared under low F127 concentration, the face-centered cubic (FCC) packed micelles at high F127 concentration, which provided orderly reaction spaces for AgNO3 and AsA reagents, dominated the growth of triangular and hexagonal prisms. The great variety in morphology is directly correlated with not only the concentration ratio between these reactants but the F127 induced kinetic mechanisms. Moreover, the greatly branched Ag nanocrystals exhibit significant surface-enhanced Raman scattering (SERS) for facilely, rapidly and effectively determining malachite green oxalate (MG) in aqueous solution. The present results provide valuable data not only for fundamental understanding of the directing effect of both F127 and AsA on the synthesis of Ag nanocrystals, but for advanced design and practical manufacturing of metals enhanced SERS sensors.
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CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.











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