Chirality-dependent balance between hydrogen bonding and London dispersion in isolated (±)-1-indanol clusters
文献信息
Jonas Altnöder, Juhyon J. Lee, Katharina E. Otto, Martin A. Suhm
The aggregation behavior of racemic and enantiopure 1-indanol has been studied by FTIR spectroscopy, resonant ion dip IR spectroscopy, and spontaneous Raman scattering in supersonic jets. This triple experimental approach, augmented by homology to related molecular fragments and dispersion-corrected DFT predictions, allows disentangling the complex spectroscopic signature in the OH stretch range. Evidence for chirality-sensitive aggregation via isolated OH⋯π bonds in competition with cooperative ⋯OH⋯OH⋯π patterns is collected. An accurate description of London dispersion forces provides the key to its explanation.
期刊推荐

Herald of the Russian Academy of Sciences

Journal of the Indian Institute of Science

Chinese Journal of Chemistry

Medicinal Chemistry Research

Topics in Catalysis

Main Group Chemistry

Critical Reviews in Solid State and Materials Sciences

Electroanalysis

Bioorganic & Medicinal Chemistry Letters

Journal of Asian Natural Products Research
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来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




