Red-light initiated atmospheric reactions of vibrationally excited molecules
文献信息
D. J. Donaldson
We present a brief review of long wavelength, red-light initiated chemistry from excited vibrational levels of the ground electronic state of atmospheric trace species. When sunlight driven electronic state reactions are not effective, photochemical processes occurring by vibrational overtone excitation have been found to be important in reactions of oxidized atmospheric compounds (acids, alcohols and peroxides) prevalent in the Earth's atmosphere. This review focuses on the fundamental energetic, mechanistic and dynamical aspects of unimolecular reactions of vibrationally excited atmospheric species. We will discuss the relevance of these red light initiated reactions to address the discrepancies between atmospheric measurements and results of standard atmospheric models.
期刊推荐

Crystallography Reports

Chemical Communications

Organic Process Research & Development

Russian Chemical Bulletin

Journal of Natural Medicines

Chemistry Education Research and Practice

Current Opinion in Solid State & Materials Science

Journal of Saudi Chemical Society

Russian Journal of General Chemistry

New Journal of Chemistry
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.
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