Hydroxymethylfurfural production from bioresources: past, present and future
文献信息
Siew Ping Teong, Guangshun Yi, Yugen Zhang
5-Hydroxymethylfurfural (HMF) has been known as a product from hexose dehydration for over 100 years and is considered to be one of the most promising platform molecules that can be converted into a variety of interesting chemicals. HMF, together with furfural and 2,5-furandicarboxylic acid (FDCA) are derivatives of furan compounds, which were listed as the top 10 value-added bio-based chemicals by the US Department of Energy. The great and increasing interest in the production of furan derivatives from biomass resources is due to the great potential of furan derivatives as feedstock for bulk chemicals and fuels. HMF can be synthesized by dehydration of all types of C6 carbohydrates, including monomeric and polymeric carbohydrates, such as fructose, glucose, sucrose, starch, inulin, cellulose, and raw biomass. Numerous improvements and milestones have been made in the dehydration process during the past 130 years. The big challenge for the process of HMF production is its suitability for industrial scale yet being cost efficient. This perspective article will review the HMF development timeline, focusing on the important events, landmark contributions, engineering and practical challenges of HMF production.
相关文献
Highly sensitive and selective light-up fluorescent probe for monitoring gallium and chromium ions in vitro and in vivo
Xiaojun He, Chenglin Wu, Yuna Qian, Yahui Li, Lilei Zhang, Feng Ding, Hong Chen
DOI: 10.1039/C9AN00625G
Direct monitoring of light mediated hyperthermia induced within mammalian tissues using surface enhanced spatially offset Raman spectroscopy (T-SESORS)
Benjamin Gardner, Pavel Matousek, Nick Stone
DOI: 10.1039/C8AN02466A
Full-color emissive carbon-dots targeting cell walls of onion for in situ imaging of heavy metal pollution
Zheng Yao, Zhiqiang Lai, Chengchi Chen, Suting Xiao, Peihui Yang
DOI: 10.1039/C9AN00418A
Potential of mid-infrared spectroscopy as a non-invasive diagnostic test in urine for endometrial or ovarian cancer
Maria Paraskevaidi, Kássio M. G. Lima, Katherine M. Ashton, Helen F. Stringfellow, Pierre L. Martin-Hirsch, Francis L. Martin
DOI: 10.1039/C8AN00027A
Aptamer immobilization on amino-functionalized metal–organic frameworks: an ultrasensitive platform for the electrochemical diagnostic of Escherichia coli O157:H7
Saba Ranjbar
DOI: 10.1039/C8AN00725J
A novel turn-on fluorescent probe for selective sensing and imaging of glutathione in live cells and organisms
Xiaodong Zhang, Ziqian Wang, Zongwei Guo, Nianzhe He, Peng Liu, Dasha Xia, Xiufen Yan, Zhichao Zhang
DOI: 10.1039/C9AN00115H
Enhancing the colorimetric detection of H2O2 and ascorbic acid on polypyrrole coated fluconazole-functionalized POMOFs
Xiao Li, Longjiang Sun, Xiya Yang, Kunfeng Zhou, Gongguo Zhang, Zhibo Tong, Jingquan Sha
DOI: 10.1039/C9AN00163H
Multi-functional derivatization of amine, hydroxyl, and carboxylate groups for metabolomic investigations of human tissue by electrospray ionization mass spectrometry
Tianjiao Huang, Richard Lee, Dawn S. Hui, James L. Edwards
DOI: 10.1039/C8AN00490K
A new method using machine learning for automated image analysis applied to chip-based digital assays
Tong Gou, Shufang Zhou, Weibo Fang, Jingjing Sun, Zhenming Hu, Haotian Shen
DOI: 10.1039/C9AN00149B
Solid phase microextraction coupled to mass spectrometry via a microfluidic open interface for rapid therapeutic drug monitoring
Nikita T. Looby, Tijana Vasiljevic, Marcin Wąsowicz, Janusz Pawliszyn
DOI: 10.1039/C9AN00041K
您可能还喜欢
如何储存8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯(CAS号:1072944-81-0)?
8-溴-4-羟基-6-(三氟甲氧基)喹啉-3-羧酸乙酯应储存在阴凉、干燥的地方,避免光照和高温。建议使用密封容器进行储存,以防止水分和空气的影响。
2,2-二(2-呋喃基)丙烷(CAS号:17920-88-6)的市场或研究趋势如何?
2,2-二(2-呋喃基)丙烷的研究趋势主要集中在新型材料的开发和应用,如高分子材料、有机光电材料等。市场趋势方面,随着环保要求的提高和新材料的应用,该化合物的需...
如何处理含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐(CAS号:475152-31-9)的废料?
对于含有螺[呋喃并[3,4-b]吡啶-5(7H),4'-哌啶]-7-酮盐酸盐的废料,应首先进行分类和分离,以减少危险物质的数量。随后,可以考虑通过化学氧化、生物...
Cinnamyl 3-aminobut-2-enoate(CAS号:113898-97-8)安全吗?
Cinnamyl 3-氨基丁-2-烯酸在接触皮肤和眼睛时可能会引起刺激。应避免吸入其粉尘和烟雾。操作时应穿戴适当的个人防护装备,如手套、护目镜和实验室外套。
反式-2-十二碳烯二酸(CAS号:6402-36-4)的市场或研究趋势如何?
反式-2-十二碳烯二酸在医药、材料科学等领域有一定的应用,但其市场相对较小。近年来,由于环保意识的提升,对环境友好型化学品的需求增加,研究倾向于开发更绿色的合成...
什么是(9ci)-1H-苯并咪唑-5-乙酸(CAS号:473895-86-2)?
(9ci)-1H-苯并咪唑-5-乙酸是一种含氮杂环化合物,其化学结构为1H-苯并咪唑-5-乙酸。该化合物具有特定的分子式C8H7NO2,属于有机酸类化合物。
酞菁蓝(CAS号:147-14-8)的主要用途是什么?
酞菁蓝主要用作颜料和染料,广泛应用于塑料、油墨、涂料、纺织品及橡胶工业中。它也用于光敏材料,如太阳能电池和光刻胶。在医疗领域,酞菁蓝因其光敏特性被用于某些光动力...
5-甲基-1,2,3,4-四氢异喹啉(CAS号:123593-99-7)安全吗?
5-甲基-1,2,3,4-四氢异喹啉在使用和储存时需要谨慎处理。它具有一定的毒性,应避免吸入其蒸气或直接接触皮肤和眼睛。操作此化合物时,建议佩戴防护眼镜、实验服...
如何处理含有3',4',5'-三甲氧基苯乙酮(CAS号:1136-86-3)的废料?
含有3',4',5'-三甲氧基苯乙酮的废液应首先确保其是否为危险废物,根据当地法规确定处理方法。通常,这类有机废液可以采用中和反应降低其pH值,然后通过蒸馏或萃...
如何储存KI-7(CAS号:1489263-00-4)?
KI-7应储存在通风良好的干燥环境中,避免光照和高温。建议使用密封容器储存,并保持在阴凉处。储存温度应控制在室温范围内,一般建议不超过25°C。避免与氧化剂接触...
来源期刊
Green Chemistry

Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.














