Functional fluorescent aramids: aromatic polyamides containing a dipicolinic acid derivative as luminescent converters and sensory materials for the fluorescence detection and quantification of Cr(vi), Fe(iii) and Cu(ii)

文献信息

发布日期 2013-05-23

DOI 10.1039/C3PY00503H

影响因子 5.582

作者

José Luis Barrio-Manso, Patricia Calvo, Félix Clemente García, Jesús Luis Pablos, Tomás Torroba, José Miguel García

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摘要

This work describes the preparation of luminescent, high-performance aromatic polyamides. The fluorescent behaviour was achieved by preparing a diacid monomer containing a fluorescent dipicolinic acid derivative and polymerising it with commercially available aromatic diacid and diamine monomers to give polyisophthalamides. These materials can be structurally compared to commercialised meta-aramid fibres [poly(m-phenylene isophthalamide), brand names: NOMEX® and Teijinconex®]. The pendant fluorescent motif provided the material with a light green fluorescence and was found to be a selective host unit for cations of environmental, biomedical and industrial significance [Cr(VI), Fe(III) and Cu(III)].

期刊推荐

Applied Organometallic Chemistry

Composites Science and Technology

Geotextiles and Geomembranes

Heterocycles

Organometallics

Journal of the Royal Society of New Zealand

Journal of Analytical Atomic Spectrometry

Corrosion Reviews

Natural Product Reports

Fire Safety Journal

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Functional fluorescent aramids: aromatic polyamides containing a dipicolinic acid derivative as luminescent converters and sensory materials for the fluorescence detection and quantification of Cr(vi), Fe(iii) and Cu(ii)

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来源期刊

Polymer Chemistry

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