The planar electric double layer capacitance for the solvent primitive model electrolyte
文献信息
Stanisław Lamperski, Monika Płuciennik, Christopher W. Outhwaite
The planar electric double layer capacitance of the solvent primitive model electrolyte is studied using simulation and two versions of the modified Poisson–Boltzmann theory. At small values of the surface charge and varying electrolyte concentration, the capacitance has a behaviour analogous to that of the restricted primitive model electrolyte. As the electrolyte concentration is increased at a fixed total packing fraction, the minimum at zero surface charge changes to a maximum. This qualitative change is predicted by both simulation and the modified Poisson–Boltzmann theories. The transition envelope, separating the change in the capacitance from a minimum to a maximum at zero surface charge, is shifted from the restricted primitive model value to higher ion densities at fixed total packing fractions.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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