Synthesis and properties of a well-defined copolymer of chlorotrifluoroethylene and N-vinylpyrrolidone by xanthate-mediated radical copolymerization under 60Co γ-ray irradiation

文献信息

发布日期 2014-07-24

DOI 10.1039/C4PY00902A

影响因子 5.582

作者

Pucheng Wang, Jingwen Dai, Lei Liu, Qibao Dong, Hu Wang, Ruke Bai

查看原文

摘要

Living/controlled radical copolymerization of chlorotrifluoroethylene and N-vinylpyrrolidone has been successfully achieved at room temperature under 60Co γ-ray irradiation in the presence of ethyl 2-(ethoxycarbonothioylthio)acetate. The living/controlled character of the polymerization was confirmed by GPC and NMR analyses, as well as the chain extension polymerization. The physical properties of the obtained polymers were investigated and the experimental results indicate that the fluorinated copolymer showed excellent film-forming characteristics and high mechanical properties. Moreover, the fluorinated amphiphilic block copolymers prepared by chain extension polymerization show good biocompatibility.

期刊推荐

Current Opinion in Solid State & Materials Science

Russian Journal of Coordination Chemistry

Acta Materialia

Drug Discovery Today

Russian Journal of Applied Chemistry

Crystallography Reports

Current Opinion in Colloid & Interface Science

New Journal of Chemistry

Russian Journal of Organic Chemistry

Organic Process Research & Development

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis and properties of a well-defined copolymer of chlorotrifluoroethylene and N-vinylpyrrolidone by xanthate-mediated radical copolymerization under 60Co γ-ray irradiation

文献信息

期刊推荐

相关文献

Highly sensitive, selective and reusable mercury(ii) ion sensor based on a ssDNA-functionalized photonic crystal film

Studies of bimolecular reaction dynamics using pulsed high-intensity vacuum-ultraviolet lasers for photoionization detection

Highly soluble energy relay dyes for dye-sensitized solar cells

Enhanced electrochemical reactions of 1,4-benzoquinone at nanoporous electrodes

Conformational preferences of furan- and thiophene-based arylamides: a combined computational and experimental study

Superior power density solid oxidefuel cells by enlarging the three-phase boundary region of a NiO–Ce0.8Gd0.2O1.9 composite anode through optimized surface structure

Extending the distance range accessed with continuous wave EPR with Gd3+spin probes at high magnetic fields

Nuclear spin–spin coupling anisotropy in the van der Waals-bonded 129Xe dimer

Impact of molecular solvophobicity vs. solvophilicity on device performances of dimeric perylene diimide based solution-processed non-fullerene organic solar cells

Dye-sensitized solar cells based on hydroquinone/benzoquinone as bio-inspired redox couple with different counter electrodes

您可能还喜欢

4,5-二甲基-2-硝基苯甲酸(CAS号：4315-14-4)的市场或研究趋势如何？

处理直接黑22(CAS号：6473-13-8)时应注意哪些实验室安全事项？

处理2,1,3-苯并噻二唑-4-基异氰酸酯(CAS号：342411-14-7)时应注意哪些实验室安全事项？

如何处理含有Δ-8,9-脱氢雌酮(CAS号：204077-66-7)的废料？

如何储存5-溴戊酸(CAS号：2067-33-6)？

4-(甲基亚磺酰基)苯胺(CAS号：22865-62-9)应用于哪些行业？

什么是1-(2-FLUOROPHENYL)-5-METHYL-1H-PYRAZOLE-4-CARBOHYDRAZIDE(CAS号：618092-58-3)？

Dauricumine(CAS号：345641-00-1)通常如何合成？

5-氰基苯酞(CAS号：82104-74-3)安全吗？

2-Methyl-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridin-5-amine(CAS号：1186502-59-9)安全吗？

来源期刊

Polymer Chemistry

推荐化合物

1-Boc-(3-carboxymethoxy)azetidine

4-[(3-Chloro-2-fluorophenyl)amino]-7-methoxy-6-quinazolinyl acetate

5-Phenyl-1-(pyridin-3-ylsulfonyl)-1H-pyrrole-3-carbaldehyde

(2R,4R)-1-Boc-4-Aminopyrrolidine-2-carboxylic acid

5-Ethyl-2,3-diphenyl-2H-tetrazol-3-ium chloride

推荐供应商