Synthesis of highly reactive polyisobutylene with FeCl3/ether complexes in hexane; kinetic and mechanistic studies

文献信息

发布日期 2014-09-12

DOI 10.1039/C4PY01039F

影响因子 5.582

作者

Rajeev Kumar, Priyadarsi De, Bin Zheng, Kuo-Wei Huang, Jack Emert, Rudolf Faust

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摘要

The kinetics and mechanism of the polymerization of isobutylene catalyzed by FeCl3·ether complexes in hexane at 0 °C were investigated. The polymerization rates increased in the diisopropyl ether< 2-chloroethyl ethyl ether < bis(2-chloroethyl) ether order, attributed to electronic effects. The polymerization rates increased with increasing initiator and catalyst concentrations. The first order plots, however, deviated from the linear suggesting that the cation concentration decreases with time. The previously proposed mechanism is inadequate to explain this finding. The decrease in the polymerization rate with time is explained by the low solubility of the H+ROR′FeCl4− complexes that precipitate during polymerization. Based on mechanistic studies the revised mechanism now also includes the equilibrium H+ROR′FeCl4− HCl + FeCl3·ROR′.

期刊推荐

European Journal of Medicinal Chemistry

Synthetic Communications

Bioorganic Chemistry

Journal of Natural Products

Applied Surface Science

Annual Review of Public Health

Progress in Materials Science

Crystal Research and Technology

Dental Materials

Organic Geochemistry

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis of highly reactive polyisobutylene with FeCl3/ether complexes in hexane; kinetic and mechanistic studies

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Polymer Chemistry

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