Synthesis of a new poly([R]-3-hydroxybutyrate) RAFT agent

文献信息

发布日期 2016-01-04

DOI 10.1039/C5PY01812A

影响因子 5.582

作者

Lu Jiang, Sing Shy Liow

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摘要

Poly[(R)-3-hydroxybutyrate] (PHB) has attracted more and more attention in biomedical applications in recent years, due to its excellent properties of sustainability, biodegradability and biocompatibility. In this work, purified natural PHB was modified by 1-hexanol through transesterification reaction to form mono-hydroxylated PHB. The kinetic process of transesterification was carefully investigated. The mono-hydroxylated PHB was reacted with the thiocarbonylthio compound to generate a biodegradable macro mono-hydroxylated PHB chain transfer agent (CTA), which could react with other monomers to produce block copolymers. The monomer, 2-dimethylaminoethyl methacrylate (DMAEMA) was chosen to demonstrate the copolymerization process and the block copolymer PHB-b-PDMAEMA was obtained.

期刊推荐

European Journal of Organic Chemistry

Environmental Toxicology and Pharmacology

Photochemical & Photobiological Sciences

Molecules

Advanced Engineering Materials

Current Pharmaceutical Biotechnology

Coloration Technology

Journal of Medical Biochemistry

Physical Chemistry Chemical Physics

Molecular Diversity

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Synthesis of a new poly([R]-3-hydroxybutyrate) RAFT agent

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来源期刊

Polymer Chemistry

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