Blending block copolymer micelles in solution; obstacles of blending

文献信息

发布日期 2016-01-26

DOI 10.1039/C5PY02006A

影响因子 5.582

作者

Daniel B. Wright, Joseph P. Patterson, Nathan C. Gianneschi, Christophe Chassenieux, Olivier Colombani, Rachel K. O'Reilly

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摘要

Amphiphilic block copolymers can assemble into a variety of structures on the nanoscale in selective solvent. The micelle blending protocol offers a simple unique route to reproducibly produce polymer nanostructures. Here we expand this blending protocol to a range of polymer micelle systems and self-assembly routes. We found by exploring a range of variables that the systems must be able to reach global equilibrium at some point for the blending protocol to be successful. Our results demonstrate the kinetic requirements, specifically core block glass transition temperature, Tg, and length of the block limiting the exchange rates, for the blending protocol which can then be applied to a wide range of polymer systems to access this simple protocol for polymer self-assembly.

期刊推荐

Letters in Organic Chemistry

Nature Methods

Physics of Life Reviews

Current Topics in Medicinal Chemistry

Current Organic Synthesis

Natural Product Research

Mini-Reviews in Organic Chemistry

Nature Materials

Medicinal Chemistry

Organic & Biomolecular Chemistry

来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Blending block copolymer micelles in solution; obstacles of blending

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