Optical characterizations of the surface states in hybrid lead–halide perovskites
文献信息
Weiguang Kong, Tao Ding, Gang Bi, Huizhen Wu
Methylammonium lead-iodide (CH3NH3PbI3, hereafter referred to as MAPbI3) perovskite has emerged as a dazzling nova in the solar cell realm. To date, the surface physics of these materials is still puzzling, but in this work, we demonstrate that the optical dynamics in MAPbI3 is primarily determined by the surface states. Pb dangling bonds on the surface of MAPbI3 introduce shallow electronic states. The carrier localization effect for these electronic states is rather weak as the lifetimes of the carriers on the iodine-poor surface are comparative to those in the interior region of MAPbI3. In contrast, rich-iodine on the surface of MAPbI3 induces deep trap centers for the carriers, which are detrimental to long carrier diffusion lengths. It is further proved that the surface passivation, which surprisingly prolongs the carrier diffusion lengths, mainly works on the rich-iodine on the surface rather than the Pb dangling bonds. This better understanding of the surface physics could provide essential information for improving the performance of photoelectronic devices based on MAPbI3 perovskites.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




