The first UV absorption band of l-tryptophan is not due to two simultaneous orthogonal electronic transitions differing in the dipole moment
文献信息
Based on UV/Vis spectroscopic evidence obtained in this work, the first band in the absorption spectrum of L-tryptophan is largely due to a single electronic transition from the ground state to the 1Lb excited state. However, emission spectra of this compound recorded at a variable temperature in ethanol, n-butanol and diethyl ether are structureless and considerably red-shifted at room temperature; also, lowering the temperature causes the emission to become structured and to undergo such a strong blue shift that it appears to be due to the 1Lb state of the compound. Based on these findings, the formation (from the excited 1Lb state) of the excited state responsible for the structureless, markedly red-shifted emission in L-tryptophan is strongly dependent not only on the viscosity of the medium, but also on its dipolarity.
相关文献
Adsorption, structure and dynamics of benzene in ordered and disordered porous carbons
Benoit Coasne, Christiane Alba-Simionesco, Gilberte Dosseh, Keith E. Gubbins
DOI: 10.1039/C0CP02205E
Compilation of all the isothermal mass/charge transport properties of the mixed conducting La2NiO4+δ at elevated temperatures
Hong-Seok Kim, Han-Ill Yoo
DOI: 10.1039/C0CP02120B
Kinetic studies of atmospherically relevant silicon chemistry. Part III: Reactions of Si+ and SiO+ with O3, and Si+ with O2
Juan C. Gómez Martín, John M. C. Plane
DOI: 10.1039/C0CP01380C
Tailored nanoporous gold for ultrahigh fluorescence enhancement
X. Y. Lang, P. F. Guan, T. Fujita, M. W. Chen
DOI: 10.1039/C0CP01571G
Scattering methods applied to soft matter
Sandra Engelskirchen, Chandrashekhar V. Kulkarni
DOI: 10.1039/C1CP90008K
Rheo-attenuated total reflectance infrared spectroscopy: a new tool to study biopolymers
Maxime Boulet-Audet, Fritz Vollrath, Chris Holland
DOI: 10.1039/C0CP02599B
DFT study of propane dehydrogenation on Pt catalyst: effects of step sites
Ming-Lei Yang, Yi-An Zhu, Chen Fan, Zhi-Jun Sui, De Chen, Xing-Gui Zhou
DOI: 10.1039/C0CP00341G
Influence of moisture content and temperature on the dielectric permittivity of zeolite NaY
Markus Kraus, Frank-Dieter Kopinke, Ulf Roland
DOI: 10.1039/C0CP02264K
High temperature shock-tube study of the reaction of gallium with ammonia
Mustapha Fikri, Metehan Bozkurt, Holger Somnitz
DOI: 10.1039/C0CP01373K
Kinetic stability of water-dispersed oil droplets encapsulated in a polyelectrolyte multilayer shell
Anton V. Sadovoy, Maxim V. Kiryukhin, Maria N. Antipina
DOI: 10.1039/C0CP01762K
您可能还喜欢
什么是3-表南美楝属二醇(CAS号:19942-04-2)?
3-表南美楝属二醇是一种具有特定立体化学结构的化合物,其分子式为C31H52O2,属于甾醇类化合物。它具有光学活性,是一种复杂的有机分子,主要存在于一些植物中。
3-羧基-5-碘苯甲酸甲酯(CAS号:50765-22-5)应用于哪些行业?
3-羧基-5-碘苯甲酸甲酯主要应用于医药行业,作为合成某些药物中间体的重要原料。此外,它还可能用于聚合物的改性、传感器的制备以及半导体材料的制备等领域。
什么是3-Bromoindolin-2-one(CAS号:22942-87-6)?
3-Bromoindolin-2-one是一种含有溴代基团的吲哚酮衍生物,分子式为C9H7BrNO。它是一种无色固体,具有一定的挥发性,熔点为158-159°C...
如何处理含有L-Lysyl-L-phenylalanyl-L-isoleucylglycyl-L-leucyl-L-methioninamide(CAS号:2990-43-4)的废料?
对于含有该化合物的废液,应先进行中和处理,然后根据其毒性和活性选择合适的处置方法。可以考虑焚烧处理或由专业的化学品废物处理公司进行无害化处理。处理过程中需注意环...
ANGIOTENSIN 1/2 + A (2 - 8)(CAS号:51833-76-2)的物理化学性质是什么?
ANGIOTENSIN 1/2 + A (2 - 8)是一种蛋白质类化合物,具有典型的蛋白质性质。它的分子量约为5900 Da。该化合物在水中具有一定的溶解性,...
如何储存2-甲基硫代嘧啶-5-硼酸频那酯(CAS号:940284-18-4)?
应将该化合物存放在阴凉干燥、通风良好的地方,避免阳光直射。建议将化合物密封保存在避光的、干燥的容器中,远离火源和高温环境。
什么是苏丹红IV氘代物 标准品(CAS号:1014689-18-9)?
苏丹红IV氘代物 标准品是一种含有氘代标记的苏丹红IV化合物,是一种用于化合物分析、结构确证以及代谢研究的标准物质。
(+)-2-Amino-6-propionamido-d3-tetrahydrobenzothiazole(CAS号:1217680-69-7)适用哪些法规指南?
该化合物需要遵循《全球化学品统一分类和标签制度》(GHS)中的分类和标签要求,具体分类需依据其毒性和物理化学性质。此外,还需要符合《欧盟化学品注册、评估、授权和...
如何储存2-氨基-2-(2-吡啶)乙酸乙酯(CAS号:55243-15-7)?
2-氨基-2-(2-吡啶)乙酸乙酯应储存于阴凉、干燥、通风良好的环境中,避免高温和光照。应使用密封容器储存,并远离易燃物、氧化剂和其他危险化学品。
3-羟基-4-甲氧基吡啶-2-羧酸(CAS号:210300-09-7)的主要用途是什么?
3-羟基-4-甲氧基吡啶-2-羧酸主要用于合成其他有机化合物,如药物合成、农药合成和染料合成等。此外,它还可用作中间体和试剂,在化学研究领域也有一定的应用。
来源期刊
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![2-[(E)-(2-Methoxyphenyl)diazenyl]-3-oxo-N-(2-oxo-2,3-dihydro-1H-benzimidazol-5-yl)butanamide structure 2-[(E)-(2-Methoxyphenyl)diazenyl]-3-oxo-N-(2-oxo-2,3-dihydro-1H-benzimidazol-5-yl)butanamide structure](https://cnstatic.chemtradehub.com/structs/821/82199-12-0-f1d0.webp)


