Crystal structure, luminescence properties, energy transfer and thermal properties of a novel color-tunable, white light-emitting phosphor Ca9−x−yCe(PO4)7:xEu2+,yMn2+
文献信息
Chao Wang, Panlai Li, Zhijun Wang, Yuansheng Sun, Jinge Cheng, Zhenling Li, Miaomiao Tian, Zhiping Yang
A series of Ca9−x−yCe(PO4)7:xEu2+,yMn2+ phosphors were synthesized by a high-temperature solid-state reaction method. The as-prepared samples were characterized by XRD and EDX measurements, which showed that Eu2+ and Mn2+ could be efficiently doped into the host. Ce3+ acts concurrently as activator and sensitizer in Ca9Ce(PO4)7, and the energy transfer mechanisms between Ce3+/Eu2+ and Ce3+/Mn2+ in Ca9Ce(PO4)7 were validated and proven to be a resonant type via dipole–quadrupole and dipole–dipole interactions, respectively. Besides, there is also energy transfer from Eu2+ to Mn2+ ions. The host, Ca9Ce(PO4)7, emits blue-white light and Ca9Ce(PO4)7:xEu2+,yMn2+ phosphors emit blue-green through white to orange-red light under near-ultraviolet radiation as a result of tuning the ratio of Eu2+/Mn2+. Ca9Ce(PO4)7:0.04Eu2+,0.08Mn2+ emits white light with CIE coordinates (0.333, 0.310), a CCT of 5446 K, and a high CRI of 81. The energy transfer efficiency between Ce3+ and Mn2+ increases significantly with temperature. These results reveal that Ca9Ce(PO4)7:Eu2+,Mn2+ may be a potential candidate for white light-emitting phosphors.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.














