![2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure](https://cnstatic.chemtradehub.com/structs/527/52788-79-1-71c1.webp "2-[2-(2-Methoxyethoxy)ethoxy]-2-methylpropane structure")
Alkyl substituted poly(p-phenylene vinylene)s by ring opening metathesis polymerisation
文献信息
发布日期
2016-08-18
DOI
10.1039/C6PY01186A
影响因子
5.582
作者
Benjamin J. Lidster, Dharam R. Kumar, Andrew M. Spring, Chin-Yang Yu, Michael L. Turner
查看原文
摘要
The ring opening metathesis polymerisation (ROMP) of three n-octyl substituted [2.2]paracyclophane-1,9-dienes, initiated by Grubbs ruthenium carbene complexes is reported. The molecular weight of the resulting alkyl-substituted poly(p-phenylene vinylene)s is determined by the monomer to initiator ratio and the polymers are isolated with relatively narrow polydispersities and control of the end groups. Only the pseudo-geminal isomer of the tetra-alkyl substituted [2.2]paracyclophane-1,9-diene was susceptible to ROMP. The optical properties of the two series of polymers was investigated.
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来源期刊
Polymer Chemistry
CiteScore:
8.6
自引率:
7.3%
年发文量:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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