Allylboration as a versatile tool for the in situ post-polymerization functionalization of 1,4-cis-poly(butadiene)

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发布日期 2016-09-23

DOI 10.1039/C6PY01388K

影响因子 5.582

作者

Hannes Leicht, Steffen Huber, Inigo Göttker-Schnetmann, Stefan Mecking

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摘要

Allylboration is a versatile tool for the post-polymerization functionalization of poly(butadiene-co-[4,4,5,5-tetramethyl-2-(3-methyl-1,3-butadienyl)-1,3,2-dioxaborolane]). Polar functionalized aldehydes HC(O)C6H4(CH2)R (R = Br, NR2, PPh3, P(O)(OEt)2) react readily with the allyl boronic acid ester groups in the copolymer without interfering with the reactive double bonds in the polymer backbone. This provides access to stereoregular poly(butadiene) functionalized with a broad range of polar groups. Functionalization proceeds under polymerization conditions and therefore does not require a prior polymer work-up.

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来源期刊

Polymer Chemistry

CiteScore: 8.6

自引率: 7.3%

年发文量: 457

Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

Allylboration as a versatile tool for the in situ post-polymerization functionalization of 1,4-cis-poly(butadiene)

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