Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides
文献信息
发布日期
2016-06-13
DOI
10.1039/C6QO00119J
影响因子
5.281
作者
Yun Liu, Hai ning Wang, Wen bo Liu, Chao-Jun Li
查看原文
摘要
Under rhodium(III) catalysis, substituted propenoic acids successfully reacted with aryl isocyanates to provide cyclic imides via direct functionalization of the β-alkenyl C–H bond followed by intramolecular cyclization. The cascade process has been corroborated by the isolated intermediate. The reaction provides direct access to cyclic imides from readily available starting materials.
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Physical Chemistry Chemical Physics
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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