Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides

文献信息

发布日期 2016-06-13

DOI 10.1039/C6QO00119J

影响因子 5.281

作者

Yun Liu, Hai ning Wang, Wen bo Liu, Chao-Jun Li

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摘要

Under rhodium(III) catalysis, substituted propenoic acids successfully reacted with aryl isocyanates to provide cyclic imides via direct functionalization of the β-alkenyl C–H bond followed by intramolecular cyclization. The cascade process has been corroborated by the isolated intermediate. The reaction provides direct access to cyclic imides from readily available starting materials.

期刊推荐

Journal of the Indian Institute of Science

Acta Metallurgica Sinica-English Letters

Chinese Journal of Chemistry

Main Group Chemistry

Bioorganic & Medicinal Chemistry Letters

Biocatalysis and Biotransformation

Herald of the Russian Academy of Sciences

Journal of Chemical Sciences

Colloid Journal

Polycyclic Aromatic Compounds

来源期刊

Organic Chemistry Frontiers

CiteScore: 7.8

自引率: 8.7%

年发文量: 724

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

Reaction of alkenecarboxylic acids with isocyanates via rhodium(iii)-catalyzed C–H activation: a versatile route to cyclic imides

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来源期刊

Organic Chemistry Frontiers

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