Site-selective oxidative C–H sulfonylation of 8-acylaminoquinolines and anilides under metal-free conditions
文献信息
发布日期
2017-01-03
DOI
10.1039/C6QO00730A
影响因子
5.281
作者
Dong Li
查看原文
摘要
A highly site-selective oxidative C–H sulfonylation method for 8-acylaminoquinolines and anilides with sulfonyl chlorides has been developed, which provided C5-sulfonylated quinolines and para-sulfonylated anilides respectively. Good functional group compatibility was showed in both amides and sulfonyl substrates. This method was only mediated by using a hypervalent iodine reagent PhI(OPiv)2 under mild conditions without any metallic catalyst or extra additives, which would provide a novel and facile methodology for synthesis of sulfone compounds.
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来源期刊
Organic Chemistry Frontiers
CiteScore:
7.8
自引率:
8.7%
年发文量:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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